Oxygen-17 nuclear magnetic resonance measurements on apatite-type lanthanum silicate (La9.33(SiO4)6O2)

Hajime Kiyono, Yuuya Matsuda, Toshihiro Shimada, Mariko Ando, Itaru Oikawa, Hideki Maekawa, Susumu Nakayama, Shinobu Ohki, Masataka Tansho, Tadashi Shimizu, Pierre Florian, Dominuqie Massiot

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

We used magic angle spinning (MAS), multiquantum (MQ)-MAS, and high-temperature (HT) nuclear magnetic resonance (NMR) measurements to investigate the oxide-ion conduction path of oxygen-17 (O-17) in apatite-type lanthanum silicate La9.33(SiO4)6O2. A highly crystalline apatite-type lanthanum silicate was specifically synthesized for the measurements. MAS and MQ-MAS NMR confirmed that four kinds of oxide-ion sites are present in the structure and showed a small extra peak (< 1%) possibly due to an interstitial site. The high-temperature measurements showed that the line shape changed and sharpened with increasing temperature from 200 °C, and the peak position shifted at 700 °C. The comparison of the results between MAS NMR (room-temperature) and HT static NMR showed the exchange of oxide ions bonded to Si (O1, O2, and O3) but the apparent exchange between the oxide ions (O1, O2, and O3) and the oxide ion at the isolated site (O4) is not observed. The exchange of the oxide ions that are bonded to Si (O1, O2, and O3) suggests that they are the main diffusion species in oxide-ion conductivity.

Original languageEnglish
Pages (from-to)64-69
Number of pages6
JournalSolid State Ionics
Volume228
DOIs
Publication statusPublished - 2012 Nov 30

Fingerprint

oxygen 17
Magnetic resonance measurement
Lanthanum
Silicates
Apatites
Apatite
apatites
lanthanum
Oxides
Magic angle spinning
silicates
Nuclear magnetic resonance
Ions
Oxygen
metal spinning
nuclear magnetic resonance
oxides
ions
Ion exchange
species diffusion

Keywords

  • Apatite
  • High-temperature NMR
  • Lanthanum silicate
  • MQ MAS
  • Oxide-ion conductor
  • Solid-state NMR

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Chemistry(all)

Cite this

Oxygen-17 nuclear magnetic resonance measurements on apatite-type lanthanum silicate (La9.33(SiO4)6O2). / Kiyono, Hajime; Matsuda, Yuuya; Shimada, Toshihiro; Ando, Mariko; Oikawa, Itaru; Maekawa, Hideki; Nakayama, Susumu; Ohki, Shinobu; Tansho, Masataka; Shimizu, Tadashi; Florian, Pierre; Massiot, Dominuqie.

In: Solid State Ionics, Vol. 228, 30.11.2012, p. 64-69.

Research output: Contribution to journalArticle

Kiyono, H, Matsuda, Y, Shimada, T, Ando, M, Oikawa, I, Maekawa, H, Nakayama, S, Ohki, S, Tansho, M, Shimizu, T, Florian, P & Massiot, D 2012, 'Oxygen-17 nuclear magnetic resonance measurements on apatite-type lanthanum silicate (La9.33(SiO4)6O2)', Solid State Ionics, vol. 228, pp. 64-69. https://doi.org/10.1016/j.ssi.2012.09.016
Kiyono, Hajime ; Matsuda, Yuuya ; Shimada, Toshihiro ; Ando, Mariko ; Oikawa, Itaru ; Maekawa, Hideki ; Nakayama, Susumu ; Ohki, Shinobu ; Tansho, Masataka ; Shimizu, Tadashi ; Florian, Pierre ; Massiot, Dominuqie. / Oxygen-17 nuclear magnetic resonance measurements on apatite-type lanthanum silicate (La9.33(SiO4)6O2). In: Solid State Ionics. 2012 ; Vol. 228. pp. 64-69.
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AU - Kiyono, Hajime

AU - Matsuda, Yuuya

AU - Shimada, Toshihiro

AU - Ando, Mariko

AU - Oikawa, Itaru

AU - Maekawa, Hideki

AU - Nakayama, Susumu

AU - Ohki, Shinobu

AU - Tansho, Masataka

AU - Shimizu, Tadashi

AU - Florian, Pierre

AU - Massiot, Dominuqie

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AB - We used magic angle spinning (MAS), multiquantum (MQ)-MAS, and high-temperature (HT) nuclear magnetic resonance (NMR) measurements to investigate the oxide-ion conduction path of oxygen-17 (O-17) in apatite-type lanthanum silicate La9.33(SiO4)6O2. A highly crystalline apatite-type lanthanum silicate was specifically synthesized for the measurements. MAS and MQ-MAS NMR confirmed that four kinds of oxide-ion sites are present in the structure and showed a small extra peak (< 1%) possibly due to an interstitial site. The high-temperature measurements showed that the line shape changed and sharpened with increasing temperature from 200 °C, and the peak position shifted at 700 °C. The comparison of the results between MAS NMR (room-temperature) and HT static NMR showed the exchange of oxide ions bonded to Si (O1, O2, and O3) but the apparent exchange between the oxide ions (O1, O2, and O3) and the oxide ion at the isolated site (O4) is not observed. The exchange of the oxide ions that are bonded to Si (O1, O2, and O3) suggests that they are the main diffusion species in oxide-ion conductivity.

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