Peculiar nonlinear elasticity of polyrotaxane gels with movable cross-links revealed by multiaxial stretching

Yohsuke Bitoh, Norio Akuzawa, Kenji Urayama, Toshikazu Takigawa, Masatoshi Kidowaki, Kohzo Ito

Research output: Contribution to journalArticle

41 Citations (Scopus)

Abstract

A peculiar rubber elasticity feature of polyrotaxane (PR) gels with cross-links capable of moving along network strands is revealed by general biaxial strain testing that varies the strains in the two orthogonal directions. The influence of the strain in one direction on the stress in the other direction in the PR gels with sufficiently low cross-link concentrations is much smaller than that in conventional elastomers and gels with fixed cross-links. The stress-strain behavior of the PR gels under various types of deformation is exceptionally close to the prediction of the neo-Hookean model with no explicit strain-coupling between the different principal directions other than that resulting from volume conservation. The minimal strain-coupling between different two directions is a pronounced feature for PR gels with movable cross-links to vary the network topology in response to imposed deformation.

Original languageEnglish
Pages (from-to)8661-8667
Number of pages7
JournalMacromolecules
Volume44
Issue number21
DOIs
Publication statusPublished - 2011 Nov 8

Fingerprint

Stretching
Elasticity
Gels
Elastomers
Rubber
polyrotaxane
Conservation
Topology
Direction compound
Testing

ASJC Scopus subject areas

  • Organic Chemistry
  • Materials Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry

Cite this

Peculiar nonlinear elasticity of polyrotaxane gels with movable cross-links revealed by multiaxial stretching. / Bitoh, Yohsuke; Akuzawa, Norio; Urayama, Kenji; Takigawa, Toshikazu; Kidowaki, Masatoshi; Ito, Kohzo.

In: Macromolecules, Vol. 44, No. 21, 08.11.2011, p. 8661-8667.

Research output: Contribution to journalArticle

Bitoh, Yohsuke ; Akuzawa, Norio ; Urayama, Kenji ; Takigawa, Toshikazu ; Kidowaki, Masatoshi ; Ito, Kohzo. / Peculiar nonlinear elasticity of polyrotaxane gels with movable cross-links revealed by multiaxial stretching. In: Macromolecules. 2011 ; Vol. 44, No. 21. pp. 8661-8667.
@article{3163e0f2e3774cec887636ea1b557416,
title = "Peculiar nonlinear elasticity of polyrotaxane gels with movable cross-links revealed by multiaxial stretching",
abstract = "A peculiar rubber elasticity feature of polyrotaxane (PR) gels with cross-links capable of moving along network strands is revealed by general biaxial strain testing that varies the strains in the two orthogonal directions. The influence of the strain in one direction on the stress in the other direction in the PR gels with sufficiently low cross-link concentrations is much smaller than that in conventional elastomers and gels with fixed cross-links. The stress-strain behavior of the PR gels under various types of deformation is exceptionally close to the prediction of the neo-Hookean model with no explicit strain-coupling between the different principal directions other than that resulting from volume conservation. The minimal strain-coupling between different two directions is a pronounced feature for PR gels with movable cross-links to vary the network topology in response to imposed deformation.",
author = "Yohsuke Bitoh and Norio Akuzawa and Kenji Urayama and Toshikazu Takigawa and Masatoshi Kidowaki and Kohzo Ito",
year = "2011",
month = "11",
day = "8",
doi = "10.1021/ma201530z",
language = "English",
volume = "44",
pages = "8661--8667",
journal = "Macromolecules",
issn = "0024-9297",
publisher = "American Chemical Society",
number = "21",

}

TY - JOUR

T1 - Peculiar nonlinear elasticity of polyrotaxane gels with movable cross-links revealed by multiaxial stretching

AU - Bitoh, Yohsuke

AU - Akuzawa, Norio

AU - Urayama, Kenji

AU - Takigawa, Toshikazu

AU - Kidowaki, Masatoshi

AU - Ito, Kohzo

PY - 2011/11/8

Y1 - 2011/11/8

N2 - A peculiar rubber elasticity feature of polyrotaxane (PR) gels with cross-links capable of moving along network strands is revealed by general biaxial strain testing that varies the strains in the two orthogonal directions. The influence of the strain in one direction on the stress in the other direction in the PR gels with sufficiently low cross-link concentrations is much smaller than that in conventional elastomers and gels with fixed cross-links. The stress-strain behavior of the PR gels under various types of deformation is exceptionally close to the prediction of the neo-Hookean model with no explicit strain-coupling between the different principal directions other than that resulting from volume conservation. The minimal strain-coupling between different two directions is a pronounced feature for PR gels with movable cross-links to vary the network topology in response to imposed deformation.

AB - A peculiar rubber elasticity feature of polyrotaxane (PR) gels with cross-links capable of moving along network strands is revealed by general biaxial strain testing that varies the strains in the two orthogonal directions. The influence of the strain in one direction on the stress in the other direction in the PR gels with sufficiently low cross-link concentrations is much smaller than that in conventional elastomers and gels with fixed cross-links. The stress-strain behavior of the PR gels under various types of deformation is exceptionally close to the prediction of the neo-Hookean model with no explicit strain-coupling between the different principal directions other than that resulting from volume conservation. The minimal strain-coupling between different two directions is a pronounced feature for PR gels with movable cross-links to vary the network topology in response to imposed deformation.

UR - http://www.scopus.com/inward/record.url?scp=80455144461&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=80455144461&partnerID=8YFLogxK

U2 - 10.1021/ma201530z

DO - 10.1021/ma201530z

M3 - Article

AN - SCOPUS:80455144461

VL - 44

SP - 8661

EP - 8667

JO - Macromolecules

JF - Macromolecules

SN - 0024-9297

IS - 21

ER -