Pervaporative separation of organic mixtures using dinitrophenyl group-containing cellulose acetate membrane

Samuel P. Kusumocahyo, Takayuki Ichikawa, Toshio Shinbo, Takashi Iwatsubo, Mitsuyoshi Kameda, Katsuhide Ohi, Yasuo Yoshimi, Toshiyuki Kanamori

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

This paper reports experimental results on pervaporation of benzene/cyclohexane mixtures and xylene isomer mixtures through a fixed-carrier membrane consisting of cellulose acetate (CA) as a base polymer and dinitrophenyl (DNP) group as a selective fixed-carrier. The result of the pervaporation of benzene/cyclohexane mixture using the unmodified CA membrane and the CA-DNP membrane showed that the DNP group was effective to increase the benzene selectivity. In the pervaporation of xylene isomer mixtures, the DNP group selectively facilitated the transport of xylene isomers through the membrane. The order of the preferentially permeating component was p-xylene > m-xylene > o-xylene.

Original languageEnglish
Pages (from-to)43-48
Number of pages6
JournalJournal of Membrane Science
Volume253
Issue number1-2
DOIs
Publication statusPublished - 2005 May 5

Keywords

  • Cellulose acetate
  • Dinitrophenyl group
  • Facilitated transport
  • Fixed-carrier membrane
  • Pervaporation

ASJC Scopus subject areas

  • Biochemistry
  • Materials Science(all)
  • Physical and Theoretical Chemistry
  • Filtration and Separation

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