Polymer-inorganic nanocomposite thin film emitters, optoelectronic chemical sensors, and energy harvesters produced by multiple-beam pulsed laser deposition

Abdalla M. Darwish, Simeon Wilson, Ashley Blackwell, Keylantra Taylor, Sergey Sarkisov, Darayas Patel, Paolo Mele, Michael W. Johnson, Xiaodong Zhang, Brent Koplitz

Research output: Chapter in Book/Report/Conference proceedingConference contribution

4 Citations (Scopus)

Abstract

Large class of new photonic devices, including light emitters, chemical sensors, and energy harvesters, can be made of the polymer-inorganic nanocomposite thin films produced by the new multiple-beam pulsed laser deposition process (MB-PLD). We describe the PLD system and the film deposition process itself, particularly the multiple-beam matrix assisted pulsed laser evaporation (MB-MAPLE) version with laser beam scanning and plume direction control. We also report on the results of the investigation of optical and performance characteristics of three types of the fabricated nanocomposite thin film devices: upconversion light emitters, chemical (ammonia) sensors, and thermoelectric energy harvesters. The emitters were made of poly(methyl methacrylate) (PMMA) film impregnated with the nanoparticles of rare-earth (RE) fluorides such as NaYF4: Yb3+, Er3+ and NaYF4: Yb3+, Ho3+. They demonstrated bright upconversion emission in visible region being pumped with a 980-nm infra-red laser. The same films, but doped with an indicator dye, were tested as ammonia sensors. They demonstrated the drop of upconversion emission (registered by a photodetector) due to the rise of the optical absorption of the indicator dye affected by ammonia. The capability of detecting fractions of one percent (molar) of ammonia was established. The thermoelectric energy harvesters were made of nanocomposite films of aluminum-doped zinc oxide (AZO) impregnated with polymer nanoparticles. The role of the nanoparticles was to reduce the thermoconductivity and increase electroconductivity thus contributing to the improvement of the thermoelectric figure-of-merit ZT.

Original languageEnglish
Title of host publicationPhotonic Fiber and Crystal Devices
Subtitle of host publicationAdvances in Materials and Innovations in Device Applications IX
EditorsShizhuo Yin, Ruyan Guo
PublisherSPIE
Volume9586
ISBN (Electronic)9781628417524
DOIs
Publication statusPublished - 2015 Jan 1
Externally publishedYes
EventPhotonic Fiber and Crystal Devices: Advances in Materials and Innovations in Device Applications IX - San Diego, United States
Duration: 2015 Aug 92015 Aug 10

Other

OtherPhotonic Fiber and Crystal Devices: Advances in Materials and Innovations in Device Applications IX
CountryUnited States
CitySan Diego
Period15/8/915/8/10

Fingerprint

Inorganic polymers
Harvesters
Nanocomposite films
Pulsed laser deposition
Chemical sensors
Ammonia
Optoelectronic devices
pulsed laser deposition
ammonia
nanocomposites
emitters
Thin films
sensors
polymers
thin films
Nanoparticles
nanoparticles
Coloring Agents
Dyes
dyes

Keywords

  • Ammonia sensors
  • Matrix assisted laser evaporation
  • Multiple beam pulsed laser deposition
  • Polymer-inorganic nanocomposite films
  • Thermoelectric energy harvesters
  • Upconversion light emitters

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Computer Science Applications
  • Applied Mathematics
  • Electrical and Electronic Engineering

Cite this

Darwish, A. M., Wilson, S., Blackwell, A., Taylor, K., Sarkisov, S., Patel, D., ... Koplitz, B. (2015). Polymer-inorganic nanocomposite thin film emitters, optoelectronic chemical sensors, and energy harvesters produced by multiple-beam pulsed laser deposition. In S. Yin, & R. Guo (Eds.), Photonic Fiber and Crystal Devices: Advances in Materials and Innovations in Device Applications IX (Vol. 9586). [958602] SPIE. https://doi.org/10.1117/12.2185498

Polymer-inorganic nanocomposite thin film emitters, optoelectronic chemical sensors, and energy harvesters produced by multiple-beam pulsed laser deposition. / Darwish, Abdalla M.; Wilson, Simeon; Blackwell, Ashley; Taylor, Keylantra; Sarkisov, Sergey; Patel, Darayas; Mele, Paolo; Johnson, Michael W.; Zhang, Xiaodong; Koplitz, Brent.

Photonic Fiber and Crystal Devices: Advances in Materials and Innovations in Device Applications IX. ed. / Shizhuo Yin; Ruyan Guo. Vol. 9586 SPIE, 2015. 958602.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Darwish, AM, Wilson, S, Blackwell, A, Taylor, K, Sarkisov, S, Patel, D, Mele, P, Johnson, MW, Zhang, X & Koplitz, B 2015, Polymer-inorganic nanocomposite thin film emitters, optoelectronic chemical sensors, and energy harvesters produced by multiple-beam pulsed laser deposition. in S Yin & R Guo (eds), Photonic Fiber and Crystal Devices: Advances in Materials and Innovations in Device Applications IX. vol. 9586, 958602, SPIE, Photonic Fiber and Crystal Devices: Advances in Materials and Innovations in Device Applications IX, San Diego, United States, 15/8/9. https://doi.org/10.1117/12.2185498
Darwish AM, Wilson S, Blackwell A, Taylor K, Sarkisov S, Patel D et al. Polymer-inorganic nanocomposite thin film emitters, optoelectronic chemical sensors, and energy harvesters produced by multiple-beam pulsed laser deposition. In Yin S, Guo R, editors, Photonic Fiber and Crystal Devices: Advances in Materials and Innovations in Device Applications IX. Vol. 9586. SPIE. 2015. 958602 https://doi.org/10.1117/12.2185498
Darwish, Abdalla M. ; Wilson, Simeon ; Blackwell, Ashley ; Taylor, Keylantra ; Sarkisov, Sergey ; Patel, Darayas ; Mele, Paolo ; Johnson, Michael W. ; Zhang, Xiaodong ; Koplitz, Brent. / Polymer-inorganic nanocomposite thin film emitters, optoelectronic chemical sensors, and energy harvesters produced by multiple-beam pulsed laser deposition. Photonic Fiber and Crystal Devices: Advances in Materials and Innovations in Device Applications IX. editor / Shizhuo Yin ; Ruyan Guo. Vol. 9586 SPIE, 2015.
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abstract = "Large class of new photonic devices, including light emitters, chemical sensors, and energy harvesters, can be made of the polymer-inorganic nanocomposite thin films produced by the new multiple-beam pulsed laser deposition process (MB-PLD). We describe the PLD system and the film deposition process itself, particularly the multiple-beam matrix assisted pulsed laser evaporation (MB-MAPLE) version with laser beam scanning and plume direction control. We also report on the results of the investigation of optical and performance characteristics of three types of the fabricated nanocomposite thin film devices: upconversion light emitters, chemical (ammonia) sensors, and thermoelectric energy harvesters. The emitters were made of poly(methyl methacrylate) (PMMA) film impregnated with the nanoparticles of rare-earth (RE) fluorides such as NaYF4: Yb3+, Er3+ and NaYF4: Yb3+, Ho3+. They demonstrated bright upconversion emission in visible region being pumped with a 980-nm infra-red laser. The same films, but doped with an indicator dye, were tested as ammonia sensors. They demonstrated the drop of upconversion emission (registered by a photodetector) due to the rise of the optical absorption of the indicator dye affected by ammonia. The capability of detecting fractions of one percent (molar) of ammonia was established. The thermoelectric energy harvesters were made of nanocomposite films of aluminum-doped zinc oxide (AZO) impregnated with polymer nanoparticles. The role of the nanoparticles was to reduce the thermoconductivity and increase electroconductivity thus contributing to the improvement of the thermoelectric figure-of-merit ZT.",
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AU - Taylor, Keylantra

AU - Sarkisov, Sergey

AU - Patel, Darayas

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N2 - Large class of new photonic devices, including light emitters, chemical sensors, and energy harvesters, can be made of the polymer-inorganic nanocomposite thin films produced by the new multiple-beam pulsed laser deposition process (MB-PLD). We describe the PLD system and the film deposition process itself, particularly the multiple-beam matrix assisted pulsed laser evaporation (MB-MAPLE) version with laser beam scanning and plume direction control. We also report on the results of the investigation of optical and performance characteristics of three types of the fabricated nanocomposite thin film devices: upconversion light emitters, chemical (ammonia) sensors, and thermoelectric energy harvesters. The emitters were made of poly(methyl methacrylate) (PMMA) film impregnated with the nanoparticles of rare-earth (RE) fluorides such as NaYF4: Yb3+, Er3+ and NaYF4: Yb3+, Ho3+. They demonstrated bright upconversion emission in visible region being pumped with a 980-nm infra-red laser. The same films, but doped with an indicator dye, were tested as ammonia sensors. They demonstrated the drop of upconversion emission (registered by a photodetector) due to the rise of the optical absorption of the indicator dye affected by ammonia. The capability of detecting fractions of one percent (molar) of ammonia was established. The thermoelectric energy harvesters were made of nanocomposite films of aluminum-doped zinc oxide (AZO) impregnated with polymer nanoparticles. The role of the nanoparticles was to reduce the thermoconductivity and increase electroconductivity thus contributing to the improvement of the thermoelectric figure-of-merit ZT.

AB - Large class of new photonic devices, including light emitters, chemical sensors, and energy harvesters, can be made of the polymer-inorganic nanocomposite thin films produced by the new multiple-beam pulsed laser deposition process (MB-PLD). We describe the PLD system and the film deposition process itself, particularly the multiple-beam matrix assisted pulsed laser evaporation (MB-MAPLE) version with laser beam scanning and plume direction control. We also report on the results of the investigation of optical and performance characteristics of three types of the fabricated nanocomposite thin film devices: upconversion light emitters, chemical (ammonia) sensors, and thermoelectric energy harvesters. The emitters were made of poly(methyl methacrylate) (PMMA) film impregnated with the nanoparticles of rare-earth (RE) fluorides such as NaYF4: Yb3+, Er3+ and NaYF4: Yb3+, Ho3+. They demonstrated bright upconversion emission in visible region being pumped with a 980-nm infra-red laser. The same films, but doped with an indicator dye, were tested as ammonia sensors. They demonstrated the drop of upconversion emission (registered by a photodetector) due to the rise of the optical absorption of the indicator dye affected by ammonia. The capability of detecting fractions of one percent (molar) of ammonia was established. The thermoelectric energy harvesters were made of nanocomposite films of aluminum-doped zinc oxide (AZO) impregnated with polymer nanoparticles. The role of the nanoparticles was to reduce the thermoconductivity and increase electroconductivity thus contributing to the improvement of the thermoelectric figure-of-merit ZT.

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