Powder synthesis and luminescence properties of green emitting Ba2LiSi7-xAlxN12-xOx:Eu2+ phosphor

Takashi Takeda, Kousuke Kato, Hajime Kiyono, Naoto Hirosaki

Research output: Contribution to journalArticle

Abstract

Single phase powders of green emitting Ba2LiSi7-xAlxN12-xOx:Eu2+ phosphor were prepared by controlling the starting compositions, annealing conditions and reaction vessels. The emission peak of Ba2LiSi7-xAlxN12-xOx:Eu2+ phosphor shifted from 502 nm to 515 nm depending on the Eu concentration. The intensity was highest with an Eu concentration of 3 at%. The phosphor showed a small thermal quenching of luminescence intensity and the integrated intensities at 200 °C and 300 °C were 100% and 96%, respectively, of the intensity observed at room temperature. The phosphor washed by hydrochloric acid solution showed a high internal quantum efficiency (QE) value of 93% with 400 nm excitation.

Original languageEnglish
Article number156358
JournalJournal of Alloys and Compounds
Volume850
DOIs
Publication statusPublished - 2021 Jan 5

Keywords

  • Luminescence
  • Nitride materials
  • Phosphors
  • Scanning electron microscopy
  • Solid state reaction
  • X-ray diffraction

ASJC Scopus subject areas

  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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