Abstract
The pressure dependent rate constant for the reaction, SiH4(g)→SiH3(g)+H was predicted using the Rice-Ramspger-Kassel-Marcus theory aided by Ab-initio molecular orbital (MO). It was calculated under conditions in which the temperatures were from 600 to 1500 K intervals of 100 K. The Arrhenius type rate expression was shown.
| Original language | English |
|---|---|
| Pages (from-to) | 520-526 |
| Number of pages | 7 |
| Journal | Nippon Kinzoku Gakkaishi/Journal of the Japan Institute of Metals |
| Volume | 63 |
| Issue number | 4 |
| DOIs | |
| Publication status | Published - 1999 Jan 1 |
ASJC Scopus subject areas
- Condensed Matter Physics
- Mechanics of Materials
- Metals and Alloys
- Materials Chemistry
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Saito, N., Hirota, M., Ishizaki, T., & Fuwa, A. (1999). Prediction of pressure dependent rate constant for the reaction, SiH4(g)→SiH3(g)+H(g), using RRKM theory aided by ab-initio MO. Nippon Kinzoku Gakkaishi/Journal of the Japan Institute of Metals, 63(4), 520-526. https://doi.org/10.2320/jinstmet1952.63.4_520