Prediction of pressure dependent rate constant for the reaction, SiH4(g)→SiH3(g)+H(g), using RRKM theory aided by ab-initio MO

Nagahiro Saito, Mitsuhito Hirota, Takahiro Ishizaki, Akio Fuwa

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Abstract

The pressure dependent rate constant for the reaction, SiH4(g)→SiH3(g)+H was predicted using the Rice-Ramspger-Kassel-Marcus theory aided by Ab-initio molecular orbital (MO). It was calculated under conditions in which the temperatures were from 600 to 1500 K intervals of 100 K. The Arrhenius type rate expression was shown.

Original languageEnglish
Pages (from-to)520-526
Number of pages7
JournalNippon Kinzoku Gakkaishi/Journal of the Japan Institute of Metals
Volume63
Issue number4
DOIs
Publication statusPublished - 1999 Jan 1

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ASJC Scopus subject areas

  • Condensed Matter Physics
  • Mechanics of Materials
  • Metals and Alloys
  • Materials Chemistry

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