Preparation and characterization of silane/Mg(OH)2 composite films prepared on flame-retardant Mg-4%Al-1%Ca alloy by steam and spin coatings

Tomohiro Miyashita; Momo Inamura; Shunsuke Kishino; Takahiro Ishizaki

doi:10.2464/jilm.70.91

Preparation and characterization of silane/Mg(OH)₂ composite films prepared on flame-retardant Mg-4%Al-1%Ca alloy by steam and spin coatings

Tomohiro Miyashita, Momo Inamura, Shunsuke Kishino, Takahiro Ishizaki

Research output: Contribution to journal › Article › peer-review

Abstract

Corrosion resistant films were prepared on Mg-4Al-1Ca (ACa41) alloy by steam coating, spin coating, or steam coating followed by spin coating. The chemical and corrosion resistant properties of the films were characterized by using SEM, XRD, FT-IR, and electrochemical methods. XRD patterns revealed that the film prepared by steam coating was composed of crystal Mg(OH)₂ and Mg-Al layered double hydroxide (LDH). FT-IR spectra showed the presence of Si-O, C-H, Mg-O, and Al-O bonds in the film prepared by steam coating followed by spin coating, resulting in the formation of silane/Mg(OH)₂ composite film. Potentiodynamic polarization curves of the film prepared by the two steps coating showed high corrosion resistance, and the corrosion current density of the composite film decreased considerably compared to those of the bare ACa41, the film prepared by steam coating or spin coating.

Original language	English
Pages (from-to)	91-96
Number of pages	6
Journal	Keikinzoku/Journal of Japan Institute of Light Metals
Volume	70
Issue number	3
DOIs	https://doi.org/10.2464/jilm.70.91
Publication status	Published - 2020

Keywords

Corrosion resistance
Flame-resistant Ca-added magnesium alloy
Magnesium hydroxide
Silane molecules
Steam coating

ASJC Scopus subject areas

Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

Access to Document

10.2464/jilm.70.91

Cite this

Preparation and characterization of silane/Mg(OH)₂ composite films prepared on flame-retardant Mg-4%Al-1%Ca alloy by steam and spin coatings. / Miyashita, Tomohiro; Inamura, Momo; Kishino, Shunsuke; Ishizaki, Takahiro.

In: Keikinzoku/Journal of Japan Institute of Light Metals, Vol. 70, No. 3, 2020, p. 91-96.

Research output: Contribution to journal › Article › peer-review

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abstract = "Corrosion resistant films were prepared on Mg-4Al-1Ca (ACa41) alloy by steam coating, spin coating, or steam coating followed by spin coating. The chemical and corrosion resistant properties of the films were characterized by using SEM, XRD, FT-IR, and electrochemical methods. XRD patterns revealed that the film prepared by steam coating was composed of crystal Mg(OH)2 and Mg-Al layered double hydroxide (LDH). FT-IR spectra showed the presence of Si-O, C-H, Mg-O, and Al-O bonds in the film prepared by steam coating followed by spin coating, resulting in the formation of silane/Mg(OH)2 composite film. Potentiodynamic polarization curves of the film prepared by the two steps coating showed high corrosion resistance, and the corrosion current density of the composite film decreased considerably compared to those of the bare ACa41, the film prepared by steam coating or spin coating.",

keywords = "Corrosion resistance, Flame-resistant Ca-added magnesium alloy, Magnesium hydroxide, Silane molecules, Steam coating",

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AU - Miyashita, Tomohiro

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AU - Kishino, Shunsuke

AU - Ishizaki, Takahiro

PY - 2020

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N2 - Corrosion resistant films were prepared on Mg-4Al-1Ca (ACa41) alloy by steam coating, spin coating, or steam coating followed by spin coating. The chemical and corrosion resistant properties of the films were characterized by using SEM, XRD, FT-IR, and electrochemical methods. XRD patterns revealed that the film prepared by steam coating was composed of crystal Mg(OH)2 and Mg-Al layered double hydroxide (LDH). FT-IR spectra showed the presence of Si-O, C-H, Mg-O, and Al-O bonds in the film prepared by steam coating followed by spin coating, resulting in the formation of silane/Mg(OH)2 composite film. Potentiodynamic polarization curves of the film prepared by the two steps coating showed high corrosion resistance, and the corrosion current density of the composite film decreased considerably compared to those of the bare ACa41, the film prepared by steam coating or spin coating.

AB - Corrosion resistant films were prepared on Mg-4Al-1Ca (ACa41) alloy by steam coating, spin coating, or steam coating followed by spin coating. The chemical and corrosion resistant properties of the films were characterized by using SEM, XRD, FT-IR, and electrochemical methods. XRD patterns revealed that the film prepared by steam coating was composed of crystal Mg(OH)2 and Mg-Al layered double hydroxide (LDH). FT-IR spectra showed the presence of Si-O, C-H, Mg-O, and Al-O bonds in the film prepared by steam coating followed by spin coating, resulting in the formation of silane/Mg(OH)2 composite film. Potentiodynamic polarization curves of the film prepared by the two steps coating showed high corrosion resistance, and the corrosion current density of the composite film decreased considerably compared to those of the bare ACa41, the film prepared by steam coating or spin coating.

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