Preparation and property of temperature responsive slide-ring gels

Masatoshi Kidowaki, Changming Zhao, Toshiyuki Kataoka, Takao Nakajima, Yohei Nagao, Kohzo Ito

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Temperature responsive property of slide-ring gels formed by crosslinking of polyrotaxane (PR), inclusion complex between alkylated α-cyclodextrin and polyethylene glycol, was studied from a viewpoint of substituents and their introducing ratio. Aqueous solutions of the alkylated PR show thermo-reversible sol-gel transition whose temperature strongly depends on the hydrophobic nature of substituents and substitution ratio. This property of the PR is reflected in the temperature dependence of volume and viscoelasticity of the slide-ring gels.

Original languageEnglish
Title of host publicationPolymer Preprints, Japan
Pages1778
Number of pages1
Volume54
Edition1
Publication statusPublished - 2005
Externally publishedYes
Event54th SPSJ Annual Meeting 2005 - Yokohama
Duration: 2005 May 252005 May 27

Other

Other54th SPSJ Annual Meeting 2005
CityYokohama
Period05/5/2505/5/27

Fingerprint

Gels
Cyclodextrins
Viscoelasticity
Crosslinking
Polyethylene glycols
Superconducting transition temperature
Sol-gels
Substitution reactions
Temperature

Keywords

  • Cyclodextrin
  • Lower critical solution temperature
  • Polyethylene glycol
  • Polyrotaxane
  • Slide-ring gel
  • Stimuli-response

ASJC Scopus subject areas

  • Engineering(all)

Cite this

Kidowaki, M., Zhao, C., Kataoka, T., Nakajima, T., Nagao, Y., & Ito, K. (2005). Preparation and property of temperature responsive slide-ring gels. In Polymer Preprints, Japan (1 ed., Vol. 54, pp. 1778)

Preparation and property of temperature responsive slide-ring gels. / Kidowaki, Masatoshi; Zhao, Changming; Kataoka, Toshiyuki; Nakajima, Takao; Nagao, Yohei; Ito, Kohzo.

Polymer Preprints, Japan. Vol. 54 1. ed. 2005. p. 1778.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Kidowaki, M, Zhao, C, Kataoka, T, Nakajima, T, Nagao, Y & Ito, K 2005, Preparation and property of temperature responsive slide-ring gels. in Polymer Preprints, Japan. 1 edn, vol. 54, pp. 1778, 54th SPSJ Annual Meeting 2005, Yokohama, 05/5/25.
Kidowaki M, Zhao C, Kataoka T, Nakajima T, Nagao Y, Ito K. Preparation and property of temperature responsive slide-ring gels. In Polymer Preprints, Japan. 1 ed. Vol. 54. 2005. p. 1778
Kidowaki, Masatoshi ; Zhao, Changming ; Kataoka, Toshiyuki ; Nakajima, Takao ; Nagao, Yohei ; Ito, Kohzo. / Preparation and property of temperature responsive slide-ring gels. Polymer Preprints, Japan. Vol. 54 1. ed. 2005. pp. 1778
@inproceedings{d658dde709e54a0ba0dd717035857a28,
title = "Preparation and property of temperature responsive slide-ring gels",
abstract = "Temperature responsive property of slide-ring gels formed by crosslinking of polyrotaxane (PR), inclusion complex between alkylated α-cyclodextrin and polyethylene glycol, was studied from a viewpoint of substituents and their introducing ratio. Aqueous solutions of the alkylated PR show thermo-reversible sol-gel transition whose temperature strongly depends on the hydrophobic nature of substituents and substitution ratio. This property of the PR is reflected in the temperature dependence of volume and viscoelasticity of the slide-ring gels.",
keywords = "Cyclodextrin, Lower critical solution temperature, Polyethylene glycol, Polyrotaxane, Slide-ring gel, Stimuli-response",
author = "Masatoshi Kidowaki and Changming Zhao and Toshiyuki Kataoka and Takao Nakajima and Yohei Nagao and Kohzo Ito",
year = "2005",
language = "English",
volume = "54",
pages = "1778",
booktitle = "Polymer Preprints, Japan",
edition = "1",

}

TY - GEN

T1 - Preparation and property of temperature responsive slide-ring gels

AU - Kidowaki, Masatoshi

AU - Zhao, Changming

AU - Kataoka, Toshiyuki

AU - Nakajima, Takao

AU - Nagao, Yohei

AU - Ito, Kohzo

PY - 2005

Y1 - 2005

N2 - Temperature responsive property of slide-ring gels formed by crosslinking of polyrotaxane (PR), inclusion complex between alkylated α-cyclodextrin and polyethylene glycol, was studied from a viewpoint of substituents and their introducing ratio. Aqueous solutions of the alkylated PR show thermo-reversible sol-gel transition whose temperature strongly depends on the hydrophobic nature of substituents and substitution ratio. This property of the PR is reflected in the temperature dependence of volume and viscoelasticity of the slide-ring gels.

AB - Temperature responsive property of slide-ring gels formed by crosslinking of polyrotaxane (PR), inclusion complex between alkylated α-cyclodextrin and polyethylene glycol, was studied from a viewpoint of substituents and their introducing ratio. Aqueous solutions of the alkylated PR show thermo-reversible sol-gel transition whose temperature strongly depends on the hydrophobic nature of substituents and substitution ratio. This property of the PR is reflected in the temperature dependence of volume and viscoelasticity of the slide-ring gels.

KW - Cyclodextrin

KW - Lower critical solution temperature

KW - Polyethylene glycol

KW - Polyrotaxane

KW - Slide-ring gel

KW - Stimuli-response

UR - http://www.scopus.com/inward/record.url?scp=33645648844&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33645648844&partnerID=8YFLogxK

M3 - Conference contribution

AN - SCOPUS:33645648844

VL - 54

SP - 1778

BT - Polymer Preprints, Japan

ER -