Radical [3 + 2] cycloaddition reaction with various alkenes using iodomethylcyclopropane derivatives as new homoallyl radical precursors

Osamu Kitagawa; Yoichiro Yamada; Hiroki Fujiwara; Takeo Taguchi

doi:10.1021/jo010950i

Radical [3 + 2] cycloaddition reaction with various alkenes using iodomethylcyclopropane derivatives as new homoallyl radical precursors

Osamu Kitagawa, Yoichiro Yamada, Hiroki Fujiwara, Takeo Taguchi

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

Radical iodine atom transfer [3 + 2] cycloaddition with various alkenes using dimethyl 2-(iodomethyl) cyclopropane-1,1-dicarboxylate and 1,1-bis(phenylsulfonyl)-2-(iodomethyl)cyclopropane as new precursors of a homoallyl radical species smoothly proceeds to give functionalized cyclopentane derivatives in good yields.

Original language	English
Pages (from-to)	922-927
Number of pages	6
Journal	Journal of Organic Chemistry
Volume	67
Issue number	3
DOIs	https://doi.org/10.1021/jo010950i
Publication status	Published - 2002 Feb 8
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry

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abstract = "Radical iodine atom transfer [3 + 2] cycloaddition with various alkenes using dimethyl 2-(iodomethyl) cyclopropane-1,1-dicarboxylate and 1,1-bis(phenylsulfonyl)-2-(iodomethyl)cyclopropane as new precursors of a homoallyl radical species smoothly proceeds to give functionalized cyclopentane derivatives in good yields.",

author = "Osamu Kitagawa and Yoichiro Yamada and Hiroki Fujiwara and Takeo Taguchi",

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AU - Kitagawa, Osamu

AU - Yamada, Yoichiro

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AU - Taguchi, Takeo

PY - 2002/2/8

Y1 - 2002/2/8

N2 - Radical iodine atom transfer [3 + 2] cycloaddition with various alkenes using dimethyl 2-(iodomethyl) cyclopropane-1,1-dicarboxylate and 1,1-bis(phenylsulfonyl)-2-(iodomethyl)cyclopropane as new precursors of a homoallyl radical species smoothly proceeds to give functionalized cyclopentane derivatives in good yields.

AB - Radical iodine atom transfer [3 + 2] cycloaddition with various alkenes using dimethyl 2-(iodomethyl) cyclopropane-1,1-dicarboxylate and 1,1-bis(phenylsulfonyl)-2-(iodomethyl)cyclopropane as new precursors of a homoallyl radical species smoothly proceeds to give functionalized cyclopentane derivatives in good yields.

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Radical [3 + 2] cycloaddition reaction with various alkenes using iodomethylcyclopropane derivatives as new homoallyl radical precursors

Abstract

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