Radical [3+2]-cycloaddition reaction with alkenes using dimethyl 2-(iodomethyl)cyclopropane-1,1-dicarboxylate as a new homoallyl radical precursor

Osamu Kitagawa, Hiroki Fujiwara, Takeo Taguchi

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

Radical iodine atom transfer [3+2]-cycloaddition with various alkenes using dimethyl 2-(iodomethyl)cyclopropane-1,1-dicarboxylate as a new precursor of homoallyl radical species smoothly proceeds to give functionalized cyclopentane derivatives in good yields.

Original languageEnglish
Pages (from-to)2165-2167
Number of pages3
JournalTetrahedron Letters
Volume42
Issue number11
DOIs
Publication statusPublished - 2001 Mar 11
Externally publishedYes

Fingerprint

Cyclopentanes
Cycloaddition
Alkenes
Iodine
Derivatives
Atoms
cyclopropane

Keywords

  • Cycloadditions
  • Cyclopentanes
  • Cyclopropanes
  • Radicals and radical reactions

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Radical [3+2]-cycloaddition reaction with alkenes using dimethyl 2-(iodomethyl)cyclopropane-1,1-dicarboxylate as a new homoallyl radical precursor. / Kitagawa, Osamu; Fujiwara, Hiroki; Taguchi, Takeo.

In: Tetrahedron Letters, Vol. 42, No. 11, 11.03.2001, p. 2165-2167.

Research output: Contribution to journalArticle

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