Radical [3+2]-cycloaddition reaction with alkenes using dimethyl 2-(iodomethyl)cyclopropane-1,1-dicarboxylate as a new homoallyl radical precursor

Osamu Kitagawa; Hiroki Fujiwara; Takeo Taguchi

doi:10.1016/S0040-4039(01)00125-3

Radical [3+2]-cycloaddition reaction with alkenes using dimethyl 2-(iodomethyl)cyclopropane-1,1-dicarboxylate as a new homoallyl radical precursor

Osamu Kitagawa, Hiroki Fujiwara, Takeo Taguchi

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

Radical iodine atom transfer [3+2]-cycloaddition with various alkenes using dimethyl 2-(iodomethyl)cyclopropane-1,1-dicarboxylate as a new precursor of homoallyl radical species smoothly proceeds to give functionalized cyclopentane derivatives in good yields.

Original language	English
Pages (from-to)	2165-2167
Number of pages	3
Journal	Tetrahedron Letters
Volume	42
Issue number	11
DOIs	https://doi.org/10.1016/S0040-4039(01)00125-3
Publication status	Published - 2001 Mar 11
Externally published	Yes

Keywords

Cycloadditions
Cyclopentanes
Cyclopropanes
Radicals and radical reactions

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(01)00125-3

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title = "Radical [3+2]-cycloaddition reaction with alkenes using dimethyl 2-(iodomethyl)cyclopropane-1,1-dicarboxylate as a new homoallyl radical precursor",

abstract = "Radical iodine atom transfer [3+2]-cycloaddition with various alkenes using dimethyl 2-(iodomethyl)cyclopropane-1,1-dicarboxylate as a new precursor of homoallyl radical species smoothly proceeds to give functionalized cyclopentane derivatives in good yields.",

keywords = "Cycloadditions, Cyclopentanes, Cyclopropanes, Radicals and radical reactions",

author = "Osamu Kitagawa and Hiroki Fujiwara and Takeo Taguchi",

year = "2001",

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doi = "10.1016/S0040-4039(01)00125-3",

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journal = "Tetrahedron Letters",

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T1 - Radical [3+2]-cycloaddition reaction with alkenes using dimethyl 2-(iodomethyl)cyclopropane-1,1-dicarboxylate as a new homoallyl radical precursor

AU - Kitagawa, Osamu

AU - Fujiwara, Hiroki

AU - Taguchi, Takeo

PY - 2001/3/11

Y1 - 2001/3/11

N2 - Radical iodine atom transfer [3+2]-cycloaddition with various alkenes using dimethyl 2-(iodomethyl)cyclopropane-1,1-dicarboxylate as a new precursor of homoallyl radical species smoothly proceeds to give functionalized cyclopentane derivatives in good yields.

AB - Radical iodine atom transfer [3+2]-cycloaddition with various alkenes using dimethyl 2-(iodomethyl)cyclopropane-1,1-dicarboxylate as a new precursor of homoallyl radical species smoothly proceeds to give functionalized cyclopentane derivatives in good yields.

KW - Cycloadditions

KW - Cyclopentanes

KW - Cyclopropanes

KW - Radicals and radical reactions

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U2 - 10.1016/S0040-4039(01)00125-3

DO - 10.1016/S0040-4039(01)00125-3

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JF - Tetrahedron Letters

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ER -

Radical [3+2]-cycloaddition reaction with alkenes using dimethyl 2-(iodomethyl)cyclopropane-1,1-dicarboxylate as a new homoallyl radical precursor

Abstract

Keywords

ASJC Scopus subject areas

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