Radical cascade reaction with 1,4-dienes and 1,4-enynes using 2-(iodomethyl)cyclopropane-1,1-dicarboxylate as a homoallyl radical precursor: One-step synthesis of bicyclo[3.3.0]octane derivatives

Osamu Kitagawa, Yoichiro Yamada, Atsushi Sugawara, Takeo Taguchi

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

(equation presented) Radical cascade reaction with various 1,4-dienes and 1,4-enynes using dimethyl 2-(iodomethyl)cyclopropane-1,1-dicarboxylate as a homoallyl radical precursor smoothly proceeds through an iodine atom transfer mechanism to give functionalized bicyclo[3.3.0]octane derivatives in good yields.

Original languageEnglish
Pages (from-to)1011-1013
Number of pages3
JournalOrganic Letters
Volume4
Issue number6
DOIs
Publication statusPublished - 2002 Mar 21
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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