Reaction of tertiary cyclopropyl silyl ethers with diethylaminosulfur trifluoride. Part 2: The Friedel-Crafts allylation and cyclopropylation of electron-rich aromatic compounds

Masayuki Kirihara, Takuya Noguchi, Hiroko Kakuda, Tatsuhiro Akimoto, Akihiro Shimajiri, Minori Morishita, Akihiko Hatano, Yoshiro Hirai

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The reaction of tertiary cyclopropyl silyl ethers with diethylaminosulfur trifluoride in electron-rich aromatic compounds causes the Friedel-Crafts alkylation to produce allylated or cyclopropylated aromatic compounds.

Original languageEnglish
Pages (from-to)3777-3780
Number of pages4
JournalTetrahedron Letters
Volume47
Issue number22
DOIs
Publication statusPublished - 2006 May 29
Externally publishedYes

Fingerprint

Allylation
Ethers
Aromatic compounds
Electrons
Alkylation
diethylaminosulfur trifluoride

Keywords

  • Cyclopropyl silyl ether
  • Diethylaminosulfur trifluoride
  • Friedel-Crafts allylation
  • Friedel-Crafts cyclopropylation

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Reaction of tertiary cyclopropyl silyl ethers with diethylaminosulfur trifluoride. Part 2 : The Friedel-Crafts allylation and cyclopropylation of electron-rich aromatic compounds. / Kirihara, Masayuki; Noguchi, Takuya; Kakuda, Hiroko; Akimoto, Tatsuhiro; Shimajiri, Akihiro; Morishita, Minori; Hatano, Akihiko; Hirai, Yoshiro.

In: Tetrahedron Letters, Vol. 47, No. 22, 29.05.2006, p. 3777-3780.

Research output: Contribution to journalArticle

Kirihara, Masayuki ; Noguchi, Takuya ; Kakuda, Hiroko ; Akimoto, Tatsuhiro ; Shimajiri, Akihiro ; Morishita, Minori ; Hatano, Akihiko ; Hirai, Yoshiro. / Reaction of tertiary cyclopropyl silyl ethers with diethylaminosulfur trifluoride. Part 2 : The Friedel-Crafts allylation and cyclopropylation of electron-rich aromatic compounds. In: Tetrahedron Letters. 2006 ; Vol. 47, No. 22. pp. 3777-3780.
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AU - Noguchi, Takuya

AU - Kakuda, Hiroko

AU - Akimoto, Tatsuhiro

AU - Shimajiri, Akihiro

AU - Morishita, Minori

AU - Hatano, Akihiko

AU - Hirai, Yoshiro

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KW - Friedel-Crafts allylation

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