Reaction temperature and time dependence of MoCl5 intercalation to few-layer graphene

Ekkaphop Ketsombun, Xiangyu Wu, Inge Asselberghs, Swati Achra, Cedric Huyghebaert, Dennis Lin, Zsolt Tokei, Kazuyoshi Ueno

Research output: Contribution to journalArticle

Abstract

The efficient MoCl5 intercalation process is required to reduce the resistance of graphene interconnects. We found that optimum intercalation temperature and time depends on the layer number of few-layer graphene. The bilayer graphene was intercalated at 175 °C without serious damage, besides that higher temperature of 200 °C was required to intercalate tri-layer graphene (TLG) with a fixed reaction time for 60 min. Although we can reduce the intercalation temperature for TLG, longer reaction time is required and higher damage is found. After considering both viewpoint of the effective doping and low damage, the high reaction temperature with short reaction time condition may be suitable for the TLG intercalation process. The stacked upper layer is considered to protect the underlying layer from chemical damage during the intercalation process and it leads to the higher activation energy for intercalation at the same time. Therefore, higher reaction temperature or longer reaction time are required for intercalating FLG with more layer numbers.

Original languageEnglish
Article numberSLLE01
JournalJapanese Journal of Applied Physics
Volume59
Issue numberSL
DOIs
Publication statusPublished - 2020 Jul 1

ASJC Scopus subject areas

  • Engineering(all)
  • Physics and Astronomy(all)

Fingerprint Dive into the research topics of 'Reaction temperature and time dependence of MoCl<sub>5</sub> intercalation to few-layer graphene'. Together they form a unique fingerprint.

  • Cite this

    Ketsombun, E., Wu, X., Asselberghs, I., Achra, S., Huyghebaert, C., Lin, D., Tokei, Z., & Ueno, K. (2020). Reaction temperature and time dependence of MoCl5 intercalation to few-layer graphene. Japanese Journal of Applied Physics, 59(SL), [SLLE01]. https://doi.org/10.35848/1347-4065/ab7e3c