Sol-gel transition of hydrophobically modified polyrotaxane

Takeshi Karino, Yasushi Okumura, Changming Zhao, Masatoshi Kidowaki, Toshiyuki Kataoka, Kohzo Ito, Mitsuhiro Shibayama

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30 Citations (Scopus)

Abstract

The sol-gel transition and thermosensitivity of methylated polyrotaxane (Me-PR) aqueous solutions were investigated by means of small-angle neutron scattering (SANS) and dynamic light scattering (DLS). It is known that water-solubility of polyrotaxane (PR), consisting of polyethylene glycol) (PEG) and a-cyclodextrin (α-CD), is very low due to stacking of neighboring α-CD molecules on a PEG chain. Methylation of the hydroxyl groups on α-CD molecules resulted in a significant improvement of water-solubility, and Me-PR exhibited a thermoreversible sol-gel transition in water depending on the degree of methylation. For low degrees of methylation (≤ 30%), a Me-PR solution was transparent even up to 80°C. On the other hand, for high degrees of methylation (≥60%), it became opaque with increasing temperature and a gelation took place at high temperature. The temperature dependence of the sliding motion of α-CD molecules along the PEG chains and the mechanism of sol-gel transition are discussed on the basis of SANS and DLS results.

Original languageEnglish
Pages (from-to)9435-9440
Number of pages6
JournalMacromolecules
Volume39
Issue number26
DOIs
Publication statusPublished - 2006 Dec 26

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

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    Karino, T., Okumura, Y., Zhao, C., Kidowaki, M., Kataoka, T., Ito, K., & Shibayama, M. (2006). Sol-gel transition of hydrophobically modified polyrotaxane. Macromolecules, 39(26), 9435-9440. https://doi.org/10.1021/ma062203z