Solid-state synthesis of thermoelectric materials in Mg-Si-Ge system

Tatsuhiko Aizawa, Renbo Song, Atsushi Yamamoto

Research output: Contribution to journalArticle

32 Citations (Scopus)

Abstract

Solid solution Mg2Si1-xGex for various concentration of germanium, x, is successfully prepared in single phase by the bulk mechanical alloying (BMA) and the hot pressing (HP). Both BMA and HP process conditions were optimized to yield high dense samples with fine, homogeneous microstructure. The electrical conductivity, the Seebeck coefficient and the thermal conductivity are measured from room temperature up to about 700 K. The Seebeck coefficient is much sensitive to the germanium content, x in Mg2Si1-xGex. The pn-transition takes place at x = 0.35 where the Seebeck coefficient drastically changes its sign. The measured band gap of Mg2Si1-xGex decreases with x from 0.71 to 0.54 eV. The figure of merit at 613 K of Mg2Si 0.6Ge0.4 reaches 0.34 × 10-3 K -1 in the case of BMA for W = 600 and HP at 773 K by 1 GPa for 3.6 ks.

Original languageEnglish
Pages (from-to)1490-1496
Number of pages7
JournalMaterials Transactions
Volume46
Issue number7
DOIs
Publication statusPublished - 2005 Jul
Externally publishedYes

Fingerprint

thermoelectric materials
Seebeck coefficient
hot pressing
Mechanical alloying
Hot pressing
Seebeck effect
alloying
Germanium
solid state
germanium
synthesis
figure of merit
Solid solutions
Thermal conductivity
Energy gap
solid solutions
thermal conductivity
microstructure
Microstructure
electrical resistivity

Keywords

  • Bulk mechanical alloying
  • Hot pressing
  • MgSiGe
  • Pn-transition
  • Solid-state synthesis
  • Thermoelectricity

ASJC Scopus subject areas

  • Materials Science(all)
  • Metals and Alloys

Cite this

Solid-state synthesis of thermoelectric materials in Mg-Si-Ge system. / Aizawa, Tatsuhiko; Song, Renbo; Yamamoto, Atsushi.

In: Materials Transactions, Vol. 46, No. 7, 07.2005, p. 1490-1496.

Research output: Contribution to journalArticle

Aizawa, Tatsuhiko ; Song, Renbo ; Yamamoto, Atsushi. / Solid-state synthesis of thermoelectric materials in Mg-Si-Ge system. In: Materials Transactions. 2005 ; Vol. 46, No. 7. pp. 1490-1496.
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