Spectroelectrochemical identification of a pentavalent uranyl tetrachloro complex in room-temperature ionic liquid

Toshinari Ogura, Koichiro Takao, Kotoe Sasaki, Tsuyoshi Arai, Yasuhisa Ikeda

Research output: Contribution to journalArticle

20 Citations (Scopus)

Abstract

Reduction of UVIO2Cl42- in a mixture of 1-ethyl-3-methylimidazolium tetrafluoroborate and its chloride at E°′ =-0.996 V vs Fc/Fc+ and 298 K affords U VO2Cl43-, which is kinetically stable and exhibits typical character of UV in the UV-vis-NIR absorption spectrum.

Original languageEnglish
Pages (from-to)10525-10527
Number of pages3
JournalInorganic Chemistry
Volume50
Issue number21
DOIs
Publication statusPublished - 2011 Nov 7

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Ionic Liquids
Chlorides
Absorption spectra
chlorides
absorption spectra
room temperature
liquids
Temperature
1-ethyl-3-methylimidazolium tetrafluoroborate

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry

Cite this

Spectroelectrochemical identification of a pentavalent uranyl tetrachloro complex in room-temperature ionic liquid. / Ogura, Toshinari; Takao, Koichiro; Sasaki, Kotoe; Arai, Tsuyoshi; Ikeda, Yasuhisa.

In: Inorganic Chemistry, Vol. 50, No. 21, 07.11.2011, p. 10525-10527.

Research output: Contribution to journalArticle

Ogura, Toshinari ; Takao, Koichiro ; Sasaki, Kotoe ; Arai, Tsuyoshi ; Ikeda, Yasuhisa. / Spectroelectrochemical identification of a pentavalent uranyl tetrachloro complex in room-temperature ionic liquid. In: Inorganic Chemistry. 2011 ; Vol. 50, No. 21. pp. 10525-10527.
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