Abstract
Ionic liquid (IL) mediated gels commonly known as ion gels or ionic gels have received remarkable attention for their advanced application in electrochemical and electromechanical devices, such as actuators, lithium batteries, electric double-layer capacitors, dye-sensitized solar cells and fuel cells. In this work we focused to determine structural properties of thiol-ene crosslinked gels both in organic solvent dimethyl sulfoxide (DMSO) and IL, 1-butyl-3-methylimidazolium bis(fluorosulfonyl)imide (BMIm FSI) combining multifunctional thiol end-crosslinkers and diacrylate monomer via thiol-ene click reaction. We investigated their mechanical properties and internal structure by estimating mesh chain densities calculated from Young’s modulus compression test and nondestructive scattering method of determining mesh size by scanning microscopic light scattering (SMILS) techniques respectively. The mesh densities of the gels were found to be highly dependent on the functionality of the thiol compound both in IL and conventional solvent, DMSO. Finally, we compared the mesh chain densities determined by the two methods and discussed the assumptions to understand the internal structure of these gels.
| Original language | English |
|---|---|
| Title of host publication | ECS Transactions |
| Editors | A. Khosla, M. Kaltenbrunner, F. D. Dos Santos, K. Fukushima, M. Yanagida, H. Furukawa, K. Ito, T.-Y. Chu, T. Saito, G. Milano, L. Nagahara, P. Sekhar, A. Kakugo, H. Matsui, T. Yoshida, M. White, Y. Masubuchi, S. Bhansali, S. Tokito, A. Nakai, T. Shiba, H. Ito, A. Masuhara |
| Publisher | Electrochemical Society Inc. |
| Pages | 427-436 |
| Number of pages | 10 |
| Edition | 1 |
| ISBN (Electronic) | 9781607685395 |
| DOIs | |
| Publication status | Published - 2019 Jan 1 |
| Event | 1st International Conference on 4D Materials and Systems, 4DMS 2018 - Yonezawa, Japan Duration: 2018 Aug 26 → 2018 Aug 30 |
Publication series
| Name | ECS Transactions |
|---|---|
| Number | 1 |
| Volume | 88 |
| ISSN (Print) | 1938-6737 |
| ISSN (Electronic) | 1938-5862 |
Conference
| Conference | 1st International Conference on 4D Materials and Systems, 4DMS 2018 |
|---|---|
| Country | Japan |
| City | Yonezawa |
| Period | 18/8/26 → 18/8/30 |
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ASJC Scopus subject areas
- Engineering(all)
Cite this
Structural analysis of multifunctional ionic gels. / Ahmed, Kumkum; Naga, Naofumi; Furukawa, Hidemitsu.
ECS Transactions. ed. / A. Khosla; M. Kaltenbrunner; F. D. Dos Santos; K. Fukushima; M. Yanagida; H. Furukawa; K. Ito; T.-Y. Chu; T. Saito; G. Milano; L. Nagahara; P. Sekhar; A. Kakugo; H. Matsui; T. Yoshida; M. White; Y. Masubuchi; S. Bhansali; S. Tokito; A. Nakai; T. Shiba; H. Ito; A. Masuhara. 1. ed. Electrochemical Society Inc., 2019. p. 427-436 (ECS Transactions; Vol. 88, No. 1).Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
}
TY - GEN
T1 - Structural analysis of multifunctional ionic gels
AU - Ahmed, Kumkum
AU - Naga, Naofumi
AU - Furukawa, Hidemitsu
PY - 2019/1/1
Y1 - 2019/1/1
N2 - Ionic liquid (IL) mediated gels commonly known as ion gels or ionic gels have received remarkable attention for their advanced application in electrochemical and electromechanical devices, such as actuators, lithium batteries, electric double-layer capacitors, dye-sensitized solar cells and fuel cells. In this work we focused to determine structural properties of thiol-ene crosslinked gels both in organic solvent dimethyl sulfoxide (DMSO) and IL, 1-butyl-3-methylimidazolium bis(fluorosulfonyl)imide (BMIm FSI) combining multifunctional thiol end-crosslinkers and diacrylate monomer via thiol-ene click reaction. We investigated their mechanical properties and internal structure by estimating mesh chain densities calculated from Young’s modulus compression test and nondestructive scattering method of determining mesh size by scanning microscopic light scattering (SMILS) techniques respectively. The mesh densities of the gels were found to be highly dependent on the functionality of the thiol compound both in IL and conventional solvent, DMSO. Finally, we compared the mesh chain densities determined by the two methods and discussed the assumptions to understand the internal structure of these gels.
AB - Ionic liquid (IL) mediated gels commonly known as ion gels or ionic gels have received remarkable attention for their advanced application in electrochemical and electromechanical devices, such as actuators, lithium batteries, electric double-layer capacitors, dye-sensitized solar cells and fuel cells. In this work we focused to determine structural properties of thiol-ene crosslinked gels both in organic solvent dimethyl sulfoxide (DMSO) and IL, 1-butyl-3-methylimidazolium bis(fluorosulfonyl)imide (BMIm FSI) combining multifunctional thiol end-crosslinkers and diacrylate monomer via thiol-ene click reaction. We investigated their mechanical properties and internal structure by estimating mesh chain densities calculated from Young’s modulus compression test and nondestructive scattering method of determining mesh size by scanning microscopic light scattering (SMILS) techniques respectively. The mesh densities of the gels were found to be highly dependent on the functionality of the thiol compound both in IL and conventional solvent, DMSO. Finally, we compared the mesh chain densities determined by the two methods and discussed the assumptions to understand the internal structure of these gels.
UR - http://www.scopus.com/inward/record.url?scp=85064980068&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85064980068&partnerID=8YFLogxK
U2 - 10.1149/08801.0427ecst
DO - 10.1149/08801.0427ecst
M3 - Conference contribution
T3 - ECS Transactions
SP - 427
EP - 436
BT - ECS Transactions
A2 - Khosla, A.
A2 - Kaltenbrunner, M.
A2 - Dos Santos, F. D.
A2 - Fukushima, K.
A2 - Yanagida, M.
A2 - Furukawa, H.
A2 - Ito, K.
A2 - Chu, T.-Y.
A2 - Saito, T.
A2 - Milano, G.
A2 - Nagahara, L.
A2 - Sekhar, P.
A2 - Kakugo, A.
A2 - Matsui, H.
A2 - Yoshida, T.
A2 - White, M.
A2 - Masubuchi, Y.
A2 - Bhansali, S.
A2 - Tokito, S.
A2 - Nakai, A.
A2 - Shiba, T.
A2 - Ito, H.
A2 - Masuhara, A.
PB - Electrochemical Society Inc.
ER -