TY - GEN
T1 - Structural analysis of multifunctional ionic gels
AU - Ahmed, Kumkum
AU - Naga, Naufumi
AU - Furukawa, Hidemitsu
N1 - Funding Information:
This study has been partly supported by the Grant-in-Aid for Scientific Research (Category A, Project No. 17H01224, etc.) from the Japan Society for the Promotion of Science (JSPS), the Center Of Innovation (COI) program from the Japan Science and Technology Agency (JST), the Strategic Innovation Creation Project (SIP) from the New Energy and Industrial Technology Development Organization (NEDO) of Japan, and the Program on Open Innovation Platform with Enterprises, Research Institute and Academia (OPERA) from the JST. Ahmed K. is supported by JSPS fellowship for young scientist in DC1 category.
Publisher Copyright:
©The Electrochemical Society.
Copyright:
Copyright 2019 Elsevier B.V., All rights reserved.
PY - 2019
Y1 - 2019
N2 - Ionic liquid (IL) mediated gels commonly known as ion gels or ionic gels have received remarkable attention for their advanced application in electrochemical and electromechanical devices, such as actuators, lithium batteries, electric double-layer capacitors, dye-sensitized solar cells and fuel cells. In this work we focused to determine structural properties of thiol-ene crosslinked gels both in organic solvent dimethyl sulfoxide (DMSO) and IL, 1-butyl-3-methylimidazolium bis(fluorosulfonyl)imide (BMIm FSI) combining multifunctional thiol end-crosslinkers and diacrylate monomer via thiol-ene click reaction. We investigated their mechanical properties and internal structure by estimating mesh chain densities calculated from Young’s modulus compression test and nondestructive scattering method of determining mesh size by scanning microscopic light scattering (SMILS) techniques respectively. The mesh densities of the gels were found to be highly dependent on the functionality of the thiol compound both in IL and conventional solvent, DMSO. Finally, we compared the mesh chain densities determined by the two methods and discussed the assumptions to understand the internal structure of these gels.
AB - Ionic liquid (IL) mediated gels commonly known as ion gels or ionic gels have received remarkable attention for their advanced application in electrochemical and electromechanical devices, such as actuators, lithium batteries, electric double-layer capacitors, dye-sensitized solar cells and fuel cells. In this work we focused to determine structural properties of thiol-ene crosslinked gels both in organic solvent dimethyl sulfoxide (DMSO) and IL, 1-butyl-3-methylimidazolium bis(fluorosulfonyl)imide (BMIm FSI) combining multifunctional thiol end-crosslinkers and diacrylate monomer via thiol-ene click reaction. We investigated their mechanical properties and internal structure by estimating mesh chain densities calculated from Young’s modulus compression test and nondestructive scattering method of determining mesh size by scanning microscopic light scattering (SMILS) techniques respectively. The mesh densities of the gels were found to be highly dependent on the functionality of the thiol compound both in IL and conventional solvent, DMSO. Finally, we compared the mesh chain densities determined by the two methods and discussed the assumptions to understand the internal structure of these gels.
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U2 - 10.1149/08801.0427ecst
DO - 10.1149/08801.0427ecst
M3 - Conference contribution
AN - SCOPUS:85064980068
T3 - ECS Transactions
SP - 427
EP - 436
BT - ECS Transactions
A2 - Nagahara, L.
A2 - Milano, G.
A2 - Masubuchi, Y.
A2 - Saito, T.
A2 - Sekhar, P.
A2 - Bhansali, S.
A2 - Dos Santos, F. D.
A2 - Fukushima, K.
A2 - Chu, T.-Y.
A2 - Tokito, S.
A2 - Nakai, A.
A2 - Shiba, T.
A2 - Ito, H.
A2 - Kaltenbrunner, M.
A2 - Matsui, H.
A2 - Khosla, A.
A2 - Furukawa, H.
A2 - Ito, K.
A2 - Kakugo, A.
A2 - White, M.
A2 - Masuhara, A.
A2 - Yanagida, M.
A2 - Yoshida, T.
PB - Electrochemical Society Inc.
T2 - 1st International Conference on 4D Materials and Systems, 4DMS 2018
Y2 - 26 August 2018 through 30 August 2018
ER -