Structural properties and thermoelectric performance of the double-filled skutterudite (Sm,Gd)y(FexNi1-x)4Sb12

Cristina Artini, Riccardo Carlini, Roberto Spotorno, Fainan Failamani, Takao Mori, Paolo Mele

Research output: Contribution to journalArticle

Abstract

The structural and thermoelectric properties of the filled skutterudite (Sm,Gd)y(FexNi1-x)4 Sb12 were investigated and critically compared to the ones in the Sm-containing system with the aim of unravelling the effect of double filling on filling fraction and thermal conductivity. Several samples (x = 0.50-0.90 and y = 0.15-0.48) were prepared by melting-sintering, and two of them were densified by spark plasma sintering in order to study their thermoelectric features. The crystallographic study enables the recognition of the role of the filler size in ruling the filling fraction and the compositional location of the p/n crossover: It has been found that the former lowers and the latter moves toward lower x values with the reduction of the filler ionic size, as a consequence of the progressively weaker interaction of the filler with the Sb12 cavity. The analysis of thermoelectric properties indicates that, despite the Sm3+/Gd3+ small mass difference, the contemporary presence of these ions in the 2a site significantly affects the thermal conductivity of both p- and n-compositions. This occurs by reducing its value with respect to the Sm-filled compound at each temperature considered, and making the overall thermoelectric performance of the system comparable to several multi-filled (Fe, Ni)-based skutterudites described in the literature.

Original languageEnglish
Article number2451
JournalMaterials
Volume12
Issue number15
DOIs
Publication statusPublished - 2019 Aug 1

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Fillers
Structural properties
Thermal conductivity
Skutterudites
Spark plasma sintering
Melting
Sintering
Ions
Chemical analysis
Temperature
zwittergent 3-12

Keywords

  • Crystal structure
  • Powder x-ray diffraction
  • Skutterudites
  • Thermal conductivity
  • Thermoelectricity

ASJC Scopus subject areas

  • Materials Science(all)

Cite this

Structural properties and thermoelectric performance of the double-filled skutterudite (Sm,Gd)y(FexNi1-x)4Sb12. / Artini, Cristina; Carlini, Riccardo; Spotorno, Roberto; Failamani, Fainan; Mori, Takao; Mele, Paolo.

In: Materials, Vol. 12, No. 15, 2451, 01.08.2019.

Research output: Contribution to journalArticle

Artini, Cristina ; Carlini, Riccardo ; Spotorno, Roberto ; Failamani, Fainan ; Mori, Takao ; Mele, Paolo. / Structural properties and thermoelectric performance of the double-filled skutterudite (Sm,Gd)y(FexNi1-x)4Sb12. In: Materials. 2019 ; Vol. 12, No. 15.
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