Study on the pressure induced charge transfer phase transition in (C 5H11)4N(FeIIFeIII(C 2O2S2)3) by means of μsR spectroscopy

Masaya Enomoto, Noriyuki Kida, Norimichi Kojima, Isao Watanabe, Takao Suzuki, Yasuyuki Ishii

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

We have investigated the magnetic properties of iron mixed-valence complexes, (n-CnH2n+1) 4N[FeIIFeIII(dto)3] (dto = C 2O2S2, n = 3, 5), in which not only a ferromagnetic transition but also a novel charge transfer phase transition (CTPT) take place [1]. This CTPT can be observed under ambient pressure for n = 3, while it appears abruptly above 0.5 GPa for n = 5 [2]. Recently, we have measured the muon spin relaxation (μSR) for the CTPT of n = 3, which revealed the dynamical process of electron-transfer between FeII and Fe III and its frequency was estimated at about 0.1 MHz [3]. To investigate the pressure induced CTPT for n = 5, we carried out the μSR measurement for n = 5 at 150 K between 0.30 and 0.64 GPa with the 4He gas-operated pressure system. The asymmetry of the muon spin relaxation for n = 5 with Cu-Be pressure cell was almost constant up to 0.55 GPa, while it rapidly decreased with increasing pressure above 0.60 GPa. This result shows that the applied pressure causes the spin fluctuation due to the CTPT, which induces the decrease of the asymmetry of muon spin relaxation. This experiment can correctly decide the phase transition pressure from the absence to the appearance of the CTPT for n = 5.

Original languageEnglish
Pages (from-to)3137-3139
Number of pages3
JournalPolyhedron
Volume30
Issue number18
DOIs
Publication statusPublished - 2011 Nov 28
Externally publishedYes

Fingerprint

Charge transfer
Phase transitions
charge transfer
Spectroscopy
spectroscopy
muons
asymmetry
Spin fluctuations
transition pressure
Magnetic properties
electron transfer
Iron
Gases
magnetic properties
valence
iron
Electrons
causes
cells
gases

Keywords

  • μSR
  • Ferromagnetism
  • Iron mixed valence complex
  • Pressure induced charge transfer phase transition

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Materials Chemistry
  • Physical and Theoretical Chemistry

Cite this

Study on the pressure induced charge transfer phase transition in (C 5H11)4N(FeIIFeIII(C 2O2S2)3) by means of μsR spectroscopy. / Enomoto, Masaya; Kida, Noriyuki; Kojima, Norimichi; Watanabe, Isao; Suzuki, Takao; Ishii, Yasuyuki.

In: Polyhedron, Vol. 30, No. 18, 28.11.2011, p. 3137-3139.

Research output: Contribution to journalArticle

Enomoto, Masaya ; Kida, Noriyuki ; Kojima, Norimichi ; Watanabe, Isao ; Suzuki, Takao ; Ishii, Yasuyuki. / Study on the pressure induced charge transfer phase transition in (C 5H11)4N(FeIIFeIII(C 2O2S2)3) by means of μsR spectroscopy. In: Polyhedron. 2011 ; Vol. 30, No. 18. pp. 3137-3139.
@article{765fa0903a93435a8574e9a1823fc9d9,
title = "Study on the pressure induced charge transfer phase transition in (C 5H11)4N(FeIIFeIII(C 2O2S2)3) by means of μsR spectroscopy",
abstract = "We have investigated the magnetic properties of iron mixed-valence complexes, (n-CnH2n+1) 4N[FeIIFeIII(dto)3] (dto = C 2O2S2, n = 3, 5), in which not only a ferromagnetic transition but also a novel charge transfer phase transition (CTPT) take place [1]. This CTPT can be observed under ambient pressure for n = 3, while it appears abruptly above 0.5 GPa for n = 5 [2]. Recently, we have measured the muon spin relaxation (μSR) for the CTPT of n = 3, which revealed the dynamical process of electron-transfer between FeII and Fe III and its frequency was estimated at about 0.1 MHz [3]. To investigate the pressure induced CTPT for n = 5, we carried out the μSR measurement for n = 5 at 150 K between 0.30 and 0.64 GPa with the 4He gas-operated pressure system. The asymmetry of the muon spin relaxation for n = 5 with Cu-Be pressure cell was almost constant up to 0.55 GPa, while it rapidly decreased with increasing pressure above 0.60 GPa. This result shows that the applied pressure causes the spin fluctuation due to the CTPT, which induces the decrease of the asymmetry of muon spin relaxation. This experiment can correctly decide the phase transition pressure from the absence to the appearance of the CTPT for n = 5.",
keywords = "μSR, Ferromagnetism, Iron mixed valence complex, Pressure induced charge transfer phase transition",
author = "Masaya Enomoto and Noriyuki Kida and Norimichi Kojima and Isao Watanabe and Takao Suzuki and Yasuyuki Ishii",
year = "2011",
month = "11",
day = "28",
doi = "10.1016/j.poly.2011.03.019",
language = "English",
volume = "30",
pages = "3137--3139",
journal = "Polyhedron",
issn = "0277-5387",
publisher = "Elsevier Limited",
number = "18",

}

TY - JOUR

T1 - Study on the pressure induced charge transfer phase transition in (C 5H11)4N(FeIIFeIII(C 2O2S2)3) by means of μsR spectroscopy

AU - Enomoto, Masaya

AU - Kida, Noriyuki

AU - Kojima, Norimichi

AU - Watanabe, Isao

AU - Suzuki, Takao

AU - Ishii, Yasuyuki

PY - 2011/11/28

Y1 - 2011/11/28

N2 - We have investigated the magnetic properties of iron mixed-valence complexes, (n-CnH2n+1) 4N[FeIIFeIII(dto)3] (dto = C 2O2S2, n = 3, 5), in which not only a ferromagnetic transition but also a novel charge transfer phase transition (CTPT) take place [1]. This CTPT can be observed under ambient pressure for n = 3, while it appears abruptly above 0.5 GPa for n = 5 [2]. Recently, we have measured the muon spin relaxation (μSR) for the CTPT of n = 3, which revealed the dynamical process of electron-transfer between FeII and Fe III and its frequency was estimated at about 0.1 MHz [3]. To investigate the pressure induced CTPT for n = 5, we carried out the μSR measurement for n = 5 at 150 K between 0.30 and 0.64 GPa with the 4He gas-operated pressure system. The asymmetry of the muon spin relaxation for n = 5 with Cu-Be pressure cell was almost constant up to 0.55 GPa, while it rapidly decreased with increasing pressure above 0.60 GPa. This result shows that the applied pressure causes the spin fluctuation due to the CTPT, which induces the decrease of the asymmetry of muon spin relaxation. This experiment can correctly decide the phase transition pressure from the absence to the appearance of the CTPT for n = 5.

AB - We have investigated the magnetic properties of iron mixed-valence complexes, (n-CnH2n+1) 4N[FeIIFeIII(dto)3] (dto = C 2O2S2, n = 3, 5), in which not only a ferromagnetic transition but also a novel charge transfer phase transition (CTPT) take place [1]. This CTPT can be observed under ambient pressure for n = 3, while it appears abruptly above 0.5 GPa for n = 5 [2]. Recently, we have measured the muon spin relaxation (μSR) for the CTPT of n = 3, which revealed the dynamical process of electron-transfer between FeII and Fe III and its frequency was estimated at about 0.1 MHz [3]. To investigate the pressure induced CTPT for n = 5, we carried out the μSR measurement for n = 5 at 150 K between 0.30 and 0.64 GPa with the 4He gas-operated pressure system. The asymmetry of the muon spin relaxation for n = 5 with Cu-Be pressure cell was almost constant up to 0.55 GPa, while it rapidly decreased with increasing pressure above 0.60 GPa. This result shows that the applied pressure causes the spin fluctuation due to the CTPT, which induces the decrease of the asymmetry of muon spin relaxation. This experiment can correctly decide the phase transition pressure from the absence to the appearance of the CTPT for n = 5.

KW - μSR

KW - Ferromagnetism

KW - Iron mixed valence complex

KW - Pressure induced charge transfer phase transition

UR - http://www.scopus.com/inward/record.url?scp=82255175281&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=82255175281&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2011.03.019

DO - 10.1016/j.poly.2011.03.019

M3 - Article

VL - 30

SP - 3137

EP - 3139

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

IS - 18

ER -