Supramolecular association of M2+?p induced by different electrostatic properties using naphthyl substituted ß-diketonate complexes (metal = Cu, Pd, Pt)

Takumi Kusakawa, Takayuki Goto, Akiko Hori

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Expanded p-conjugated coordination complexes, [M(L2)2] (M = Cu2+, Pd2+, and Pt2+; L2= dinaphthoylmethanido-), were prepared and the different metal characteristics were found due to the supramolecular associations: [Cu(L2)2] shows a remarkable M2+?p interaction (3.249 Å) inducing the cationicity of Cu2+and the strength of the interactions clearly decreases for the Pd2+and Pt2+ions (3.785 and 4.610 Å), indicating their electron-rich and nucleophilic characteristics.

Original languageEnglish
Pages (from-to)3090-3094
Number of pages5
JournalCrystEngComm
Volume22
Issue number18
DOIs
Publication statusPublished - 2020 Mar 14

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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