Synthesis and crystal structures of fluorinated β-diketonate metal (Al3+, Co2+, Ni2+, and Cu2+) complexes

Akiko Hori, Ayaka Shinohe, Shohei Takatani, Takeshi K. Miyamoto

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Abstract

Co2+, Ni2+, and Cu2+ complexes with bis(pentafluorobenzoyl)methanide (L, C6F5COCHCOC 6F5 -) were prepared from [Al(L)3], which was directly synthesized from AlCl3, pentafluorobenzoyl chloride, and vinyl acetate under N2 atmosphere. The complexation of L with Co2+ and Ni2+ ions gave [M2(L) 4(OH2)2] (M = Co and Ni) and that with Cu 2+ ion gave [Cu(L)2].

Original languageEnglish
Pages (from-to)96-98
Number of pages3
JournalBulletin of the Chemical Society of Japan
Volume82
Issue number1
DOIs
Publication statusPublished - 2009
Externally publishedYes

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Crystal structure
Metals
Ions
Complexation
aluminum chloride
vinyl acetate
pentafluorobenzoyl chloride

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Synthesis and crystal structures of fluorinated β-diketonate metal (Al3+, Co2+, Ni2+, and Cu2+) complexes. / Hori, Akiko; Shinohe, Ayaka; Takatani, Shohei; Miyamoto, Takeshi K.

In: Bulletin of the Chemical Society of Japan, Vol. 82, No. 1, 2009, p. 96-98.

Research output: Contribution to journalArticle

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AU - Miyamoto, Takeshi K.

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Y1 - 2009

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AB - Co2+, Ni2+, and Cu2+ complexes with bis(pentafluorobenzoyl)methanide (L, C6F5COCHCOC 6F5 -) were prepared from [Al(L)3], which was directly synthesized from AlCl3, pentafluorobenzoyl chloride, and vinyl acetate under N2 atmosphere. The complexation of L with Co2+ and Ni2+ ions gave [M2(L) 4(OH2)2] (M = Co and Ni) and that with Cu 2+ ion gave [Cu(L)2].

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