Synthesis of a rhenium complex appending a cyclodextrin unit on a ligand

Asao Nakamura, Satoshi Okutsu, Yuji Oda, Akihiko Ueno, Fujio Toda

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Abstract

A supramolecular species has been designed for studying the mechanism of long-range electron transfer through non-covalent bonding. A rhenium complex with a cyclodextrin unit on the side arm of a ligand has been synthesized. The rhenium complex trapped N,N-diethylanilline into its cavity, and the luminescence from the host complex was quenched by the guest.

Original languageEnglish
Pages (from-to)7241-7244
Number of pages4
JournalTetrahedron Letters
Volume35
Issue number39
DOIs
Publication statusPublished - 1994 Sep 26

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Keywords

  • Cyclodextrin
  • Electron transfer
  • Inclusion
  • Rhenium complex
  • Supramolecule

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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