Synthesis of a rhenium complex appending a cyclodextrin unit on a ligand

Asao Nakamura; Satoshi Okutsu; Yuji Oda; Akihiko Ueno; Fujio Toda

doi:10.1016/0040-4039(94)85371-1

Synthesis of a rhenium complex appending a cyclodextrin unit on a ligand

Asao Nakamura, Satoshi Okutsu, Yuji Oda, Akihiko Ueno, Fujio Toda

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

A supramolecular species has been designed for studying the mechanism of long-range electron transfer through non-covalent bonding. A rhenium complex with a cyclodextrin unit on the side arm of a ligand has been synthesized. The rhenium complex trapped N,N-diethylanilline into its cavity, and the luminescence from the host complex was quenched by the guest.

Original language	English
Pages (from-to)	7241-7244
Number of pages	4
Journal	Tetrahedron Letters
Volume	35
Issue number	39
DOIs	https://doi.org/10.1016/0040-4039(94)85371-1
Publication status	Published - 1994 Sept 26
Externally published	Yes

Keywords

Cyclodextrin
Electron transfer
Inclusion
Rhenium complex
Supramolecule

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/0040-4039(94)85371-1

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abstract = "A supramolecular species has been designed for studying the mechanism of long-range electron transfer through non-covalent bonding. A rhenium complex with a cyclodextrin unit on the side arm of a ligand has been synthesized. The rhenium complex trapped N,N-diethylanilline into its cavity, and the luminescence from the host complex was quenched by the guest.",

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AU - Nakamura, Asao

AU - Okutsu, Satoshi

AU - Oda, Yuji

AU - Ueno, Akihiko

AU - Toda, Fujio

PY - 1994/9/26

Y1 - 1994/9/26

N2 - A supramolecular species has been designed for studying the mechanism of long-range electron transfer through non-covalent bonding. A rhenium complex with a cyclodextrin unit on the side arm of a ligand has been synthesized. The rhenium complex trapped N,N-diethylanilline into its cavity, and the luminescence from the host complex was quenched by the guest.

AB - A supramolecular species has been designed for studying the mechanism of long-range electron transfer through non-covalent bonding. A rhenium complex with a cyclodextrin unit on the side arm of a ligand has been synthesized. The rhenium complex trapped N,N-diethylanilline into its cavity, and the luminescence from the host complex was quenched by the guest.

KW - Cyclodextrin

KW - Electron transfer

KW - Inclusion

KW - Rhenium complex

KW - Supramolecule

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 39

ER -

Synthesis of a rhenium complex appending a cyclodextrin unit on a ligand

Abstract

Keywords

ASJC Scopus subject areas

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