TEM observation of oxide scale formed on TiC single crystals with different faces

Hajime Kiyono, S. Shimada, K. Sugawara, A. Christensen

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

Cross-sectional observation of the oxide scale formed by oxidation of TiC single crystals with (100), (110) and (111) faces at 1500 °C for 30 min in a mixed gas of Ar/O2 (PO2=0.08 kPa) was performed by transmission electron microscope (TEM). The oxide scale was composed of outer (zone 2) and inner (zone 1) subscales. TEM and selected area electron diffraction combined with X-ray energy dispersion analysis showed that the zone 2 consists of rutile and pores and the zone 1 of carbon and titanium oxide, identified as Ti3O5 in the oxide scale formed on the (110) face. Zone 1 formed on the (100) and (111) faces showed crisscross patterns, in contrast to the (110) with the wavy lamellar pattern.

Original languageEnglish
Pages (from-to)373-380
Number of pages8
JournalSolid State Ionics
Volume160
Issue number3-4
DOIs
Publication statusPublished - 2003 Jun
Externally publishedYes

Fingerprint

Oxides
Electron microscopes
electron microscopes
Single crystals
oxides
single crystals
Titanium oxides
Electron diffraction
Carbon
Gases
titanium oxides
rutile
X rays
Oxidation
electron diffraction
porosity
oxidation
carbon
gases
x rays

Keywords

  • Microstructure
  • Oxidation
  • Oxide scale
  • Single crystal
  • TEM
  • TiC

ASJC Scopus subject areas

  • Electrochemistry
  • Physical and Theoretical Chemistry
  • Energy Engineering and Power Technology
  • Materials Chemistry
  • Condensed Matter Physics

Cite this

TEM observation of oxide scale formed on TiC single crystals with different faces. / Kiyono, Hajime; Shimada, S.; Sugawara, K.; Christensen, A.

In: Solid State Ionics, Vol. 160, No. 3-4, 06.2003, p. 373-380.

Research output: Contribution to journalArticle

Kiyono, Hajime ; Shimada, S. ; Sugawara, K. ; Christensen, A. / TEM observation of oxide scale formed on TiC single crystals with different faces. In: Solid State Ionics. 2003 ; Vol. 160, No. 3-4. pp. 373-380.
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