Terahertz vibrational spectra of metallocene

Jun ichi Nishizawa; Takenori Tanno; Tadao Tanabe; Ken Suto

doi:10.1016/j.jorganchem.2005.12.066

Terahertz vibrational spectra of metallocene

Jun ichi Nishizawa, Takenori Tanno, Tadao Tanabe, Ken Suto

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

The terahertz transmission spectra of crystalline metallocenes and decamethyl metallocene were clearly measured in the range of 0.7-6.2 THz by a recently developed GaP Raman terahertz spectrometer. The low-frequency mode of ring-metal-ring bending and CH₃ out-of-plane oscillation were observed, and the force constants of bending were estimated from the absorption frequencies based on a three-body model.

Original language	English
Pages (from-to)	2479-2482
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	691
Issue number	11
DOIs	https://doi.org/10.1016/j.jorganchem.2005.12.066
Publication status	Published - 2006 May 15
Externally published	Yes

Keywords

Deuteration
Metallocene
Spectroscopy
Terahertz wave
Vibrational mode

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.jorganchem.2005.12.066

Cite this

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title = "Terahertz vibrational spectra of metallocene",

abstract = "The terahertz transmission spectra of crystalline metallocenes and decamethyl metallocene were clearly measured in the range of 0.7-6.2 THz by a recently developed GaP Raman terahertz spectrometer. The low-frequency mode of ring-metal-ring bending and CH3 out-of-plane oscillation were observed, and the force constants of bending were estimated from the absorption frequencies based on a three-body model.",

keywords = "Deuteration, Metallocene, Spectroscopy, Terahertz wave, Vibrational mode",

author = "Nishizawa, {Jun ichi} and Takenori Tanno and Tadao Tanabe and Ken Suto",

note = "Funding Information: We thank Dr. T. Sasaki for constructing the spectrometric system and Mr. T. Kimura and Mr. T. Yoshida for their technical support with the measurements. This study was conducted as part of the Terahertz Optics Project for Medications led by J. Nishizawa and organized by Ministry of Education, Culture, Sports, Science and Technology of Japan.",

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doi = "10.1016/j.jorganchem.2005.12.066",

language = "English",

volume = "691",

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TY - JOUR

T1 - Terahertz vibrational spectra of metallocene

AU - Nishizawa, Jun ichi

AU - Tanno, Takenori

AU - Tanabe, Tadao

AU - Suto, Ken

N1 - Funding Information: We thank Dr. T. Sasaki for constructing the spectrometric system and Mr. T. Kimura and Mr. T. Yoshida for their technical support with the measurements. This study was conducted as part of the Terahertz Optics Project for Medications led by J. Nishizawa and organized by Ministry of Education, Culture, Sports, Science and Technology of Japan.

PY - 2006/5/15

Y1 - 2006/5/15

N2 - The terahertz transmission spectra of crystalline metallocenes and decamethyl metallocene were clearly measured in the range of 0.7-6.2 THz by a recently developed GaP Raman terahertz spectrometer. The low-frequency mode of ring-metal-ring bending and CH3 out-of-plane oscillation were observed, and the force constants of bending were estimated from the absorption frequencies based on a three-body model.

AB - The terahertz transmission spectra of crystalline metallocenes and decamethyl metallocene were clearly measured in the range of 0.7-6.2 THz by a recently developed GaP Raman terahertz spectrometer. The low-frequency mode of ring-metal-ring bending and CH3 out-of-plane oscillation were observed, and the force constants of bending were estimated from the absorption frequencies based on a three-body model.

KW - Deuteration

KW - Metallocene

KW - Spectroscopy

KW - Terahertz wave

KW - Vibrational mode

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U2 - 10.1016/j.jorganchem.2005.12.066

DO - 10.1016/j.jorganchem.2005.12.066

M3 - Article

AN - SCOPUS:33646157749

SN - 0022-328X

VL - 691

SP - 2479

EP - 2482

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 11

ER -

Terahertz vibrational spectra of metallocene

Abstract

Keywords

ASJC Scopus subject areas

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