Tetraphenylborate ion selective electrode based on plasticized poly(vinyl chloride) membrane containing no ion-exchange site and its application to potentiometric titration

Takashi Masadome; Toshihiko Imato; Nobuhiko Ishibasm

doi:10.2116/bunsekikagaku.36.8_508

Tetraphenylborate ion selective electrode based on plasticized poly(vinyl chloride) membrane containing no ion-exchange site and its application to potentiometric titration

Takashi Masadome, Toshihiko Imato, Nobuhiko Ishibasm

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

The o-nitrophenyl octyl ether (o-NPOE)-plasticized PVC membrane electrode shows the linear response with potential slope of 50 mV per decade for tetraphenylborate (TPB^-) ion from 10^-5 M to 10^-2 M. The response time of the electrode is in the order of a few seconds. The electrode can be used in wide pH range, and is highly selective to the TPB^- ion over inorganic anions. The electrode is suitable as the end-point detector in the potentiometric titration of quaternary ammonium salts and potassium ion.

Original language	English
Pages (from-to)	508-510
Number of pages	3
Journal	Bunseki Kagaku
Volume	36
Issue number	8
DOIs	https://doi.org/10.2116/bunsekikagaku.36.8_508
Publication status	Published - 1987
Externally published	Yes

Keywords

0-nitrophenyl octyl ether-plasticized poly (vinyl chloride) membrane electrode
potentiometric titration
tetraphenylborate ion selective electrode

ASJC Scopus subject areas

Analytical Chemistry

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10.2116/bunsekikagaku.36.8_508

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title = "Tetraphenylborate ion selective electrode based on plasticized poly(vinyl chloride) membrane containing no ion-exchange site and its application to potentiometric titration",

abstract = "The o-nitrophenyl octyl ether (o-NPOE)-plasticized PVC membrane electrode shows the linear response with potential slope of 50 mV per decade for tetraphenylborate (TPB-) ion from 10-5 M to 10-2 M. The response time of the electrode is in the order of a few seconds. The electrode can be used in wide pH range, and is highly selective to the TPB- ion over inorganic anions. The electrode is suitable as the end-point detector in the potentiometric titration of quaternary ammonium salts and potassium ion.",

keywords = "0-nitrophenyl octyl ether-plasticized poly (vinyl chloride) membrane electrode, potentiometric titration, tetraphenylborate ion selective electrode",

author = "Takashi Masadome and Toshihiko Imato and Nobuhiko Ishibasm",

year = "1987",

doi = "10.2116/bunsekikagaku.36.8_508",

language = "English",

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journal = "Bunseki Kagaku",

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publisher = "Japan Society for Analytical Chemistry",

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T1 - Tetraphenylborate ion selective electrode based on plasticized poly(vinyl chloride) membrane containing no ion-exchange site and its application to potentiometric titration

AU - Masadome, Takashi

AU - Imato, Toshihiko

AU - Ishibasm, Nobuhiko

PY - 1987

Y1 - 1987

N2 - The o-nitrophenyl octyl ether (o-NPOE)-plasticized PVC membrane electrode shows the linear response with potential slope of 50 mV per decade for tetraphenylborate (TPB-) ion from 10-5 M to 10-2 M. The response time of the electrode is in the order of a few seconds. The electrode can be used in wide pH range, and is highly selective to the TPB- ion over inorganic anions. The electrode is suitable as the end-point detector in the potentiometric titration of quaternary ammonium salts and potassium ion.

AB - The o-nitrophenyl octyl ether (o-NPOE)-plasticized PVC membrane electrode shows the linear response with potential slope of 50 mV per decade for tetraphenylborate (TPB-) ion from 10-5 M to 10-2 M. The response time of the electrode is in the order of a few seconds. The electrode can be used in wide pH range, and is highly selective to the TPB- ion over inorganic anions. The electrode is suitable as the end-point detector in the potentiometric titration of quaternary ammonium salts and potassium ion.

KW - 0-nitrophenyl octyl ether-plasticized poly (vinyl chloride) membrane electrode

KW - potentiometric titration

KW - tetraphenylborate ion selective electrode

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JO - Bunseki Kagaku

JF - Bunseki Kagaku

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Tetraphenylborate ion selective electrode based on plasticized poly(vinyl chloride) membrane containing no ion-exchange site and its application to potentiometric titration

Abstract

Keywords

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