The effect of photo-irradiation in hydrolysis and condensation of silicon alkoxide

Sachiko Okusaki; Tomoji Ohishi

doi:10.1016/S0022-3093(02)02054-9

The effect of photo-irradiation in hydrolysis and condensation of silicon alkoxide

Sachiko Okusaki, Tomoji Ohishi

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

A silicon alkoxide-water-ethanol mixed solution was irradiated with ultraviolet rays, and the change of the silicon alkoxide molecular structure was evaluated by ²⁹Si nuclear magnetic resonance and Fourier transform infrared spectroscopies. Silicon alkoxide was hydrolyzed and the Si-OH bonds were produced by UV irradiation without any chemical catalyst for hydrolysis. The Si-O-Si bonds were also produced, and viscosity of the alkoxide solution became higher due to condensation of alkoxide.

Original language	English
Pages (from-to)	311-313
Number of pages	3
Journal	Journal of Non-Crystalline Solids
Volume	319
Issue number	3
DOIs	https://doi.org/10.1016/S0022-3093(02)02054-9
Publication status	Published - 2003 May 15

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Materials Chemistry

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abstract = "A silicon alkoxide-water-ethanol mixed solution was irradiated with ultraviolet rays, and the change of the silicon alkoxide molecular structure was evaluated by 29Si nuclear magnetic resonance and Fourier transform infrared spectroscopies. Silicon alkoxide was hydrolyzed and the Si-OH bonds were produced by UV irradiation without any chemical catalyst for hydrolysis. The Si-O-Si bonds were also produced, and viscosity of the alkoxide solution became higher due to condensation of alkoxide.",

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AB - A silicon alkoxide-water-ethanol mixed solution was irradiated with ultraviolet rays, and the change of the silicon alkoxide molecular structure was evaluated by 29Si nuclear magnetic resonance and Fourier transform infrared spectroscopies. Silicon alkoxide was hydrolyzed and the Si-OH bonds were produced by UV irradiation without any chemical catalyst for hydrolysis. The Si-O-Si bonds were also produced, and viscosity of the alkoxide solution became higher due to condensation of alkoxide.

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JF - Journal of Non-Crystalline Solids

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ER -

The effect of photo-irradiation in hydrolysis and condensation of silicon alkoxide

Abstract

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