Abstract
An appending moiety of modified cyclodextrins acts as an intramolecular guest and forms a self-inclusion complex in aqueous solution. In this study, the stability of self-inclusion complexes of modified cyclodextrins which have a p-dimethylaminobenzene moiety was analyzed by fluorescent decay analyses, and the factor that determines the stability of the self-inclusion complex was determined by a computational approach. The self-inclusion form is stabilized mainly due to van der Waals interaction between the appending moiety and the cyclodextrin ring.
| Original language | English |
|---|---|
| Pages (from-to) | 79-93 |
| Number of pages | 15 |
| Journal | Journal of Inclusion Phenomena |
| Volume | 36 |
| Issue number | 1 |
| Publication status | Published - 2000 Jan |
| Externally published | Yes |
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Keywords
- Fluorescence
- Inclusion complex
- Modified cyclodextrin
- Molecular mechanics
ASJC Scopus subject areas
- Chemistry(all)
- Condensed Matter Physics
Cite this
The stability of self-inclusion complexes of cyclodextrin derivatives bearing a p-dimethylaminobenze moiety. / Tanabe, Tetsuya; Usui, Shinji; Nakamura, Asao; Ueno, Akihiko.
In: Journal of Inclusion Phenomena, Vol. 36, No. 1, 01.2000, p. 79-93.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - The stability of self-inclusion complexes of cyclodextrin derivatives bearing a p-dimethylaminobenze moiety
AU - Tanabe, Tetsuya
AU - Usui, Shinji
AU - Nakamura, Asao
AU - Ueno, Akihiko
PY - 2000/1
Y1 - 2000/1
N2 - An appending moiety of modified cyclodextrins acts as an intramolecular guest and forms a self-inclusion complex in aqueous solution. In this study, the stability of self-inclusion complexes of modified cyclodextrins which have a p-dimethylaminobenzene moiety was analyzed by fluorescent decay analyses, and the factor that determines the stability of the self-inclusion complex was determined by a computational approach. The self-inclusion form is stabilized mainly due to van der Waals interaction between the appending moiety and the cyclodextrin ring.
AB - An appending moiety of modified cyclodextrins acts as an intramolecular guest and forms a self-inclusion complex in aqueous solution. In this study, the stability of self-inclusion complexes of modified cyclodextrins which have a p-dimethylaminobenzene moiety was analyzed by fluorescent decay analyses, and the factor that determines the stability of the self-inclusion complex was determined by a computational approach. The self-inclusion form is stabilized mainly due to van der Waals interaction between the appending moiety and the cyclodextrin ring.
KW - Fluorescence
KW - Inclusion complex
KW - Modified cyclodextrin
KW - Molecular mechanics
UR - http://www.scopus.com/inward/record.url?scp=0033636213&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0033636213&partnerID=8YFLogxK
M3 - Article
VL - 36
SP - 79
EP - 93
JO - Journal of Inclusion Phenomena and Macrocyclic Chemistry
JF - Journal of Inclusion Phenomena and Macrocyclic Chemistry
SN - 1388-3127
IS - 1
ER -