Three p-xylene-solvated pseudopolymorphs of bis[1,3-bis(pentafluorophenyl)propane-1,3-dionato]copper(II)

Akiko Hori, Kyosuke Nakajima, Hidetaka Yuge

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The Cu<sup>2+</sup> ions in the title compounds, namely bis[1,3-bis(pentafluorophenyl)propane-1,3-dionato-κ<sup>2</sup> O,O′]copper(II) p-xylene n-solvate, [Cu(C<inf>15</inf>HF<inf>10</inf>O<inf>2</inf>)<inf>2</inf>]·nC<inf>8</inf>H<inf>10</inf>, with n = 1, (I), n = 2, (II), and n = 4, (III), are coordinated by two 1,3-bis(pentafluorophenyl)propane-1,3-dionate ligands. The coordination complexes of (I) and (II) have crystallographic inversion symmetry at the Cu atom and the p-xylene molecule in (I) also lies across an inversion centre. The p-xylene molecules in (I) and (II) interact with the pentafluorophenyl groups of the complex via arene-perfluoroarene interactions. In the crystal of (III), two of the p-xylene molecules interact with the pentafluorophenyl groups via arene-perfluoroarene interactions. The other two p-xylene molecules are located on the CuO<inf>4</inf> coordination plane, forming a uniform cavity produced by metal⋯π interactions.

Original languageEnglish
Pages (from-to)960-964
Number of pages5
JournalActa Crystallographica Section C: Structural Chemistry
Volume70
DOIs
Publication statusPublished - 2014 Oct 15
Externally publishedYes

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Keywords

  • 1 3-bis(pentafluorophenyl)propane-1 3-dionate
  • arene-perfluoroarene interactions
  • copper complexes
  • crystal structure
  • metal⋯π interactions
  • pseudopolymorphs
  • variable solvation

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry
  • Condensed Matter Physics

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