Abstract
(Chemical Equation Presented) Extreme macrocyclization! An ultramacrocyclic structure with 238 non-hydrogen atoms in its backbone is obtained quantitatively through the reversible catenation of a double-loop compound that contains PdII-clipped coordination rings at both ends (see structure). The PdII ring can be regarded as a nanoscale reaction center that is available for connecting nano-scopic components without high entropy costs.
| Original language | English |
|---|---|
| Pages (from-to) | 4896-4899 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 44 |
| Issue number | 31 |
| DOIs | |
| Publication status | Published - 2005 Aug 5 |
| Externally published | Yes |
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Keywords
- Catenanes
- Molecular recognition
- Palladium
- Self-assembly
- Supramolecular chemistry
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Ultramacrocyclization through reversible catenation. / Hori, Akiko; Sawada, Tomohisa; Yamashita, Ken Ichi; Fujita, Makoto.
In: Angewandte Chemie - International Edition, Vol. 44, No. 31, 05.08.2005, p. 4896-4899.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Ultramacrocyclization through reversible catenation
AU - Hori, Akiko
AU - Sawada, Tomohisa
AU - Yamashita, Ken Ichi
AU - Fujita, Makoto
PY - 2005/8/5
Y1 - 2005/8/5
N2 - (Chemical Equation Presented) Extreme macrocyclization! An ultramacrocyclic structure with 238 non-hydrogen atoms in its backbone is obtained quantitatively through the reversible catenation of a double-loop compound that contains PdII-clipped coordination rings at both ends (see structure). The PdII ring can be regarded as a nanoscale reaction center that is available for connecting nano-scopic components without high entropy costs.
AB - (Chemical Equation Presented) Extreme macrocyclization! An ultramacrocyclic structure with 238 non-hydrogen atoms in its backbone is obtained quantitatively through the reversible catenation of a double-loop compound that contains PdII-clipped coordination rings at both ends (see structure). The PdII ring can be regarded as a nanoscale reaction center that is available for connecting nano-scopic components without high entropy costs.
KW - Catenanes
KW - Molecular recognition
KW - Palladium
KW - Self-assembly
KW - Supramolecular chemistry
UR - http://www.scopus.com/inward/record.url?scp=23744503054&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=23744503054&partnerID=8YFLogxK
U2 - 10.1002/anie.200501559
DO - 10.1002/anie.200501559
M3 - Article
VL - 44
SP - 4896
EP - 4899
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 31
ER -