Water-soluble inclusion complexes of [60]fullerene derivatives using γ-cyclodextrin

Atsushi Ikeda; Tomoya Genmoto; Naotake Maekubo; Jun Ichi Kikuchi; Motofusa Akiyama; Takayuki Mochizuki; Shuhei Kotani; Toshifumi Konishi

doi:10.1246/cl.2010.1256

Water-soluble inclusion complexes of [60]fullerene derivatives using γ-cyclodextrin

Atsushi Ikeda, Tomoya Genmoto, Naotake Maekubo, Jun Ichi Kikuchi, Motofusa Akiyama, Takayuki Mochizuki, Shuhei Kotani, Toshifumi Konishi

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

Pyrrolidine and N,N-dimethylpyrrolidinium derivatives of C₆₀ could be solubilized in water with the aid of γ-cyclodextrin. The complexes were found to be soluble in water at high concentrations over 1.5 mM. These solubility values are significantly higher than those of other C ₆₀ derivatives reported previously. Furthermore, these solutions are stable for at least one month at room temperature.

Original language	English
Pages (from-to)	1256-1257
Number of pages	2
Journal	Chemistry Letters
Volume	39
Issue number	12
DOIs	https://doi.org/10.1246/cl.2010.1256
Publication status	Published - 2010 Dec 13

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Chemistry(all)

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AU - Ikeda, Atsushi

AU - Genmoto, Tomoya

AU - Maekubo, Naotake

AU - Kikuchi, Jun Ichi

AU - Akiyama, Motofusa

AU - Mochizuki, Takayuki

AU - Kotani, Shuhei

AU - Konishi, Toshifumi

PY - 2010/12/13

Y1 - 2010/12/13

N2 - Pyrrolidine and N,N-dimethylpyrrolidinium derivatives of C60 could be solubilized in water with the aid of γ-cyclodextrin. The complexes were found to be soluble in water at high concentrations over 1.5 mM. These solubility values are significantly higher than those of other C 60 derivatives reported previously. Furthermore, these solutions are stable for at least one month at room temperature.

AB - Pyrrolidine and N,N-dimethylpyrrolidinium derivatives of C60 could be solubilized in water with the aid of γ-cyclodextrin. The complexes were found to be soluble in water at high concentrations over 1.5 mM. These solubility values are significantly higher than those of other C 60 derivatives reported previously. Furthermore, these solutions are stable for at least one month at room temperature.

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ER -

Water-soluble inclusion complexes of [60]fullerene derivatives using γ-cyclodextrin

Abstract

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