TY - JOUR
T1 - A complex hydride lithium superionic conductor for high-energy-density all-solid-state lithium metal batteries
AU - Kim, Sangryun
AU - Oguchi, Hiroyuki
AU - Toyama, Naoki
AU - Sato, Toyoto
AU - Takagi, Shigeyuki
AU - Otomo, Toshiya
AU - Arunkumar, Dorai
AU - Kuwata, Naoaki
AU - Kawamura, Junichi
AU - Orimo, Shin ichi
N1 - Funding Information:
This work was supported by JSPS KAKENHI (Grant–in–Aid for Research Activity Start–up, 17H06519 and Grants–in–Aid for Scientific Research on Innovative Areas “Hydrogenomics”, JP18H05513 and JP18H05518), the Collaborative Research Center on Energy Materials in IMR (E–IMR), and Advanced Target Project–4 of WPI–AIMR, Tohoku University. The authors would like to thank H. Ohmiya and N. Warifune for technical assistance (Tohoku University).
Publisher Copyright:
© 2019, The Author(s).
PY - 2019/12/1
Y1 - 2019/12/1
N2 - All-solid-state batteries incorporating lithium metal anode have the potential to address the energy density issues of conventional lithium-ion batteries that use flammable organic liquid electrolytes and low-capacity carbonaceous anodes. However, they suffer from high lithium ion transfer resistance, mainly due to the instability of the solid electrolytes against lithium metal, limiting their use in practical cells. Here, we report a complex hydride lithium superionic conductor, 0.7Li(CB9H10)–0.3Li(CB11H12), with excellent stability against lithium metal and a high conductivity of 6.7 × 10−3 S cm−1 at 25 °C. This complex hydride exhibits stable lithium plating/stripping reaction with negligible interfacial resistance (<1 Ω cm2) at 0.2 mA cm−2, enabling all-solid-state lithium-sulfur batteries with high energy density (>2500 Wh kg−1) at a high current density of 5016 mA g−1. The present study opens up an unexplored research area in the field of solid electrolyte materials, contributing to the development of high-energy-density batteries.
AB - All-solid-state batteries incorporating lithium metal anode have the potential to address the energy density issues of conventional lithium-ion batteries that use flammable organic liquid electrolytes and low-capacity carbonaceous anodes. However, they suffer from high lithium ion transfer resistance, mainly due to the instability of the solid electrolytes against lithium metal, limiting their use in practical cells. Here, we report a complex hydride lithium superionic conductor, 0.7Li(CB9H10)–0.3Li(CB11H12), with excellent stability against lithium metal and a high conductivity of 6.7 × 10−3 S cm−1 at 25 °C. This complex hydride exhibits stable lithium plating/stripping reaction with negligible interfacial resistance (<1 Ω cm2) at 0.2 mA cm−2, enabling all-solid-state lithium-sulfur batteries with high energy density (>2500 Wh kg−1) at a high current density of 5016 mA g−1. The present study opens up an unexplored research area in the field of solid electrolyte materials, contributing to the development of high-energy-density batteries.
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U2 - 10.1038/s41467-019-09061-9
DO - 10.1038/s41467-019-09061-9
M3 - Article
C2 - 30842419
AN - SCOPUS:85062614039
SN - 2041-1723
VL - 10
JO - Nature Communications
JF - Nature Communications
IS - 1
M1 - 1081
ER -