A facile synthesis of gem-difluorinated heterocyclic compounds using anodic fluorination of 2-cyano-1-methylpyrrole as a key step

Toshiki Tajima, Toshio Fuchigami

研究成果: Article

8 引用 (Scopus)

抜粋

Anodic fluorination of 2-cyano-1-methylpyrrole 1 using Et3N·5HF in an undivided cell provided 5,5-difluoro-1-methyl-3-pyrrolin-2-one (5a). The Diels-Alder reaction of 5a with various dienes was successfully carried out to provide gem-difluorinated heterocyclic compounds in excellent yields.

元の言語English
ページ(範囲)2597-2600
ページ数4
ジャーナルSynthesis
発行部数17
DOI
出版物ステータスPublished - 2002 1 1
外部発表Yes

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

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