A remarkable stereoselectivity switching upon solid-state versus solution-phase enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylic acid mediated by native and 3,6-anhydro-γ-cyclodextrins

Cheng Yang, Masaki Nishijima, Asao Nakamura, Tadashi Mori, Takehiko Wada, Yoshihisa Inoue

研究成果: Article

27 引用 (Scopus)

抜粋

The enantiodifferentiating [4+4] photocyclodimerization of anthracenecarboxylic acid (AC) mediated by native, mono- and di-3,6-anhydro-γ-cyclodextrins was investigated in both aqueous solution and solid-state. The solid-state photolyses gave inherently disfavored head-to-head photodimers in much higher chemical and optical yields than in the aqueous solution.

元の言語English
ページ(範囲)4357-4360
ページ数4
ジャーナルTetrahedron Letters
48
発行部数25
DOI
出版物ステータスPublished - 2007 6 18
外部発表Yes

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

フィンガープリント A remarkable stereoselectivity switching upon solid-state versus solution-phase enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylic acid mediated by native and 3,6-anhydro-γ-cyclodextrins' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

  • これを引用