A remarkable stereoselectivity switching upon solid-state versus solution-phase enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylic acid mediated by native and 3,6-anhydro-γ-cyclodextrins

Cheng Yang; Masaki Nishijima; Asao Nakamura; Tadashi Mori; Takehiko Wada; Yoshihisa Inoue

doi:10.1016/j.tetlet.2007.04.104

A remarkable stereoselectivity switching upon solid-state versus solution-phase enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylic acid mediated by native and 3,6-anhydro-γ-cyclodextrins

Cheng Yang, Masaki Nishijima, Asao Nakamura, Tadashi Mori, Takehiko Wada, Yoshihisa Inoue

研究成果: Article › 査読

30 被引用数 (Scopus)

抄録

The enantiodifferentiating [4+4] photocyclodimerization of anthracenecarboxylic acid (AC) mediated by native, mono- and di-3,6-anhydro-γ-cyclodextrins was investigated in both aqueous solution and solid-state. The solid-state photolyses gave inherently disfavored head-to-head photodimers in much higher chemical and optical yields than in the aqueous solution.

本文言語	English
ページ（範囲）	4357-4360
ページ数	4
ジャーナル	Tetrahedron Letters
巻	48
号	25
DOI	https://doi.org/10.1016/j.tetlet.2007.04.104
出版ステータス	Published - 2007 6 18
外部発表	はい

ASJC Scopus subject areas

生化学
創薬
有機化学

文献へのアクセス

10.1016/j.tetlet.2007.04.104

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フィンガープリント

「A remarkable stereoselectivity switching upon solid-state versus solution-phase enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylic acid mediated by native and 3,6-anhydro-γ-cyclodextrins」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

Yang, C., Nishijima, M., Nakamura, A., Mori, T., Wada, T., & Inoue, Y. (2007). A remarkable stereoselectivity switching upon solid-state versus solution-phase enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylic acid mediated by native and 3,6-anhydro-γ-cyclodextrins. Tetrahedron Letters, 48(25), 4357-4360. https://doi.org/10.1016/j.tetlet.2007.04.104

A remarkable stereoselectivity switching upon solid-state versus solution-phase enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylic acid mediated by native and 3,6-anhydro-γ-cyclodextrins. / Yang, Cheng; Nishijima, Masaki; Nakamura, Asao; Mori, Tadashi; Wada, Takehiko; Inoue, Yoshihisa.

In: Tetrahedron Letters, Vol. 48, No. 25, 18.06.2007, p. 4357-4360.

研究成果: Article › 査読

Yang, C, Nishijima, M, Nakamura, A, Mori, T, Wada, T & Inoue, Y 2007, 'A remarkable stereoselectivity switching upon solid-state versus solution-phase enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylic acid mediated by native and 3,6-anhydro-γ-cyclodextrins', Tetrahedron Letters, vol. 48, no. 25, pp. 4357-4360. https://doi.org/10.1016/j.tetlet.2007.04.104

Yang, Cheng ; Nishijima, Masaki ; Nakamura, Asao ; Mori, Tadashi ; Wada, Takehiko ; Inoue, Yoshihisa. / A remarkable stereoselectivity switching upon solid-state versus solution-phase enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylic acid mediated by native and 3,6-anhydro-γ-cyclodextrins. In: Tetrahedron Letters. 2007 ; Vol. 48, No. 25. pp. 4357-4360.

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abstract = "The enantiodifferentiating [4+4] photocyclodimerization of anthracenecarboxylic acid (AC) mediated by native, mono- and di-3,6-anhydro-γ-cyclodextrins was investigated in both aqueous solution and solid-state. The solid-state photolyses gave inherently disfavored head-to-head photodimers in much higher chemical and optical yields than in the aqueous solution.",

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AU - Yang, Cheng

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AU - Mori, Tadashi

AU - Wada, Takehiko

AU - Inoue, Yoshihisa

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