Additive-salt effect on low detection limit and slope sensitivity in response of potassium- and sodium-selective neutral carrier based electrodes and their liquid-membrane based ion-sensitive field-effect transistor

Shin Ichi Wakida, Takashi Masadome, Toshihiko Imato, Yasuhiko Shibutani, Kenji Yakabe, Toshiyuki Shono, Yasukazu Asano

研究成果: Article査読

18 被引用数 (Scopus)

抄録

The remarkable effect of additive salts on low detection limits as weir as slope sensitivities were observed for the response characteristics of bis(crown) and valinomycin based poly(vinyl chloride) (PVC) membrane electrodes. The low detection limits and the slope sensitivities for bis(crown) and valinomycin based PVC membrane electrodes were improved apparently as the hydrophobicity of the additive salts increases. In order to clarify the effect of additive salts of the PVC membrane electrodes, the response characteristics of liquid-membrane, based K+ and Na+-ISEs, which were fabricated by using micro-ion-sensitive field-effect transistors (μ- ISFETs), were evaluated. The low detection limits and the slope sensitivities in the responses of the neutral-carrier based K+ and Na+-μ-ISFETs also changed remarkably with the kind as well as the ConcentratiOn of the additive salts.

本文言語English
ページ(範囲)47-51
ページ数5
ジャーナルAnalytical Sciences
15
1
DOI
出版ステータスPublished - 1999 1
外部発表はい

ASJC Scopus subject areas

  • 分析化学

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