Amperometric biosensor with composites of carbon nanotube, hexaamineruthenium(III)chloride, and plasma-polymerized film

Tatsuya Hoshino, Takahiro Inoue, Hitoshi Muguruma

研究成果: Article査読

2 被引用数 (Scopus)

抄録

A novel fabrication approach for the amperometric biosensor composed of carbon nanotubes (CNT), a plasma-polymerized film (PPF), hexamineruthenium(III) chloride (RU), and enzyme glucose oxidase (GOD) is reported. The configuration of the electrochemical electrode is multilayer films which contain sputtered gold, lower acetonitrile PPF, CNT, RU, GOD, and upper acetonitrile PPF, sequentially. First, PPF deposited on Au acts as a permselective membrane and as a scaffold for CNT layer formation. Second, PPF directly deposited on GOD acts as a matrix for enzyme immobilization. To facilitate the electrochemical communication between the CNT layer and GOD, CNT was treated with nitrogen plasma. The electron transfer mediator RU play a role as the mediator, in which the electron caused by enzymatic reaction transports to the electrode. The synergy between the electron transfer mediator and CNT provides benefits in terms of lowering the operational potential and enhancing the sensitivity (current). The optimized glucose biosensor revealed a sensitivity of 3.4 μA mM-1 cm-2 at +0.4V vs. Ag/AgCl, linear dynamic range of 2.5-19 mM, and a response time of 6 s.

本文言語English
ページ(範囲)1536-1540
ページ数5
ジャーナルIEICE Transactions on Electronics
E96-C
12
DOI
出版ステータスPublished - 2013 12

ASJC Scopus subject areas

  • 電子材料、光学材料、および磁性材料
  • 電子工学および電気工学

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