An electrolytic system based on the anion exchange reaction between KCl and an anion exchange resin

Atsushi Nakajima; Toshiki Tajima

doi:10.1016/j.elecom.2009.04.002

An electrolytic system based on the anion exchange reaction between KCl and an anion exchange resin

Atsushi Nakajima, Toshiki Tajima

研究成果: Article › 査読

2 被引用数 (Scopus)

抄録

We have developed a novel electrolytic system based on the anion exchange reaction between KCl and Amberlyst A26. It was demonstrated by preparative electrolysis experiments as well as cyclic voltammetry that the anion exchange reaction offers a unique electrolytic system for electroreduction of organic compounds. On the basis of the electrolytic system, electroreduction of aromatic carbonyl compounds was successfully achieved by using an undivided cell to provide the corresponding coupling products as pinacols in good to high yields with high diastereoselectivity.

本文言語	English
ページ（範囲）	1199-1202
ページ数	4
ジャーナル	Electrochemistry Communications
巻	11
号	6
DOI	https://doi.org/10.1016/j.elecom.2009.04.002
出版ステータス	Published - 2009 6
外部発表	はい

ASJC Scopus subject areas

Electrochemistry

文献へのアクセス

10.1016/j.elecom.2009.04.002

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引用スタイル

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title = "An electrolytic system based on the anion exchange reaction between KCl and an anion exchange resin",

abstract = "We have developed a novel electrolytic system based on the anion exchange reaction between KCl and Amberlyst A26. It was demonstrated by preparative electrolysis experiments as well as cyclic voltammetry that the anion exchange reaction offers a unique electrolytic system for electroreduction of organic compounds. On the basis of the electrolytic system, electroreduction of aromatic carbonyl compounds was successfully achieved by using an undivided cell to provide the corresponding coupling products as pinacols in good to high yields with high diastereoselectivity.",

keywords = "Anion exchange reaction, Anion exchange resin, Electroreduction, Potassium chloride, Supporting electrolyte",

author = "Atsushi Nakajima and Toshiki Tajima",

note = "Funding Information: This work was supported by MEXT{\textquoteright}s program “Promotion of Environmental Improvement for Independence of Young Researchers” under the Special Coordination Funds for Promoting Science and Technology. A.N. thanks a Grant-in-Aid for JSPS Fellows.",

year = "2009",

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doi = "10.1016/j.elecom.2009.04.002",

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AU - Nakajima, Atsushi

AU - Tajima, Toshiki

N1 - Funding Information: This work was supported by MEXT’s program “Promotion of Environmental Improvement for Independence of Young Researchers” under the Special Coordination Funds for Promoting Science and Technology. A.N. thanks a Grant-in-Aid for JSPS Fellows.

PY - 2009/6

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N2 - We have developed a novel electrolytic system based on the anion exchange reaction between KCl and Amberlyst A26. It was demonstrated by preparative electrolysis experiments as well as cyclic voltammetry that the anion exchange reaction offers a unique electrolytic system for electroreduction of organic compounds. On the basis of the electrolytic system, electroreduction of aromatic carbonyl compounds was successfully achieved by using an undivided cell to provide the corresponding coupling products as pinacols in good to high yields with high diastereoselectivity.

AB - We have developed a novel electrolytic system based on the anion exchange reaction between KCl and Amberlyst A26. It was demonstrated by preparative electrolysis experiments as well as cyclic voltammetry that the anion exchange reaction offers a unique electrolytic system for electroreduction of organic compounds. On the basis of the electrolytic system, electroreduction of aromatic carbonyl compounds was successfully achieved by using an undivided cell to provide the corresponding coupling products as pinacols in good to high yields with high diastereoselectivity.

KW - Anion exchange reaction

KW - Anion exchange resin

KW - Electroreduction

KW - Potassium chloride

KW - Supporting electrolyte

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