抄録
We have developed a novel electrolytic system based on the anion exchange reaction between KCl and Amberlyst A26. It was demonstrated by preparative electrolysis experiments as well as cyclic voltammetry that the anion exchange reaction offers a unique electrolytic system for electroreduction of organic compounds. On the basis of the electrolytic system, electroreduction of aromatic carbonyl compounds was successfully achieved by using an undivided cell to provide the corresponding coupling products as pinacols in good to high yields with high diastereoselectivity.
| 元の言語 | English |
|---|---|
| ページ（範囲） | 1199-1202 |
| ページ数 | 4 |
| ジャーナル | Electrochemistry Communications |
| 巻 | 11 |
| 発行部数 | 6 |
| DOI | |
| 出版物ステータス | Published - 2009 6 |
| 外部発表 | Yes |
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ASJC Scopus subject areas
- Electrochemistry
これを引用
An electrolytic system based on the anion exchange reaction between KCl and an anion exchange resin. / Nakajima, Atsushi; Tajima, Toshiki.
：: Electrochemistry Communications, 巻 11, 番号 6, 06.2009, p. 1199-1202.研究成果: Article
}
TY - JOUR
T1 - An electrolytic system based on the anion exchange reaction between KCl and an anion exchange resin
AU - Nakajima, Atsushi
AU - Tajima, Toshiki
PY - 2009/6
Y1 - 2009/6
N2 - We have developed a novel electrolytic system based on the anion exchange reaction between KCl and Amberlyst A26. It was demonstrated by preparative electrolysis experiments as well as cyclic voltammetry that the anion exchange reaction offers a unique electrolytic system for electroreduction of organic compounds. On the basis of the electrolytic system, electroreduction of aromatic carbonyl compounds was successfully achieved by using an undivided cell to provide the corresponding coupling products as pinacols in good to high yields with high diastereoselectivity.
AB - We have developed a novel electrolytic system based on the anion exchange reaction between KCl and Amberlyst A26. It was demonstrated by preparative electrolysis experiments as well as cyclic voltammetry that the anion exchange reaction offers a unique electrolytic system for electroreduction of organic compounds. On the basis of the electrolytic system, electroreduction of aromatic carbonyl compounds was successfully achieved by using an undivided cell to provide the corresponding coupling products as pinacols in good to high yields with high diastereoselectivity.
KW - Anion exchange reaction
KW - Anion exchange resin
KW - Electroreduction
KW - Potassium chloride
KW - Supporting electrolyte
UR - http://www.scopus.com/inward/record.url?scp=67349177734&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=67349177734&partnerID=8YFLogxK
U2 - 10.1016/j.elecom.2009.04.002
DO - 10.1016/j.elecom.2009.04.002
M3 - Article
AN - SCOPUS:67349177734
VL - 11
SP - 1199
EP - 1202
JO - Electrochemistry Communications
JF - Electrochemistry Communications
SN - 1388-2481
IS - 6
ER -