Anodic acyloxylation based on the acid-base reactions between acetic acid or trifluoroacetic acid and solid-supported bases

Toshiki Tajima, Yuichiro Kishi, Atsushi Nakajima

研究成果: Article

13 引用 (Scopus)

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We have developed a novel electrolytic system for anodic acyloxylation based on the acid-base reactions between acetic acid or trifluoroacetic acid and solid-supported bases. On the basis of the electrolytic system, anodic acyloxylation of organic compounds, which even have considerably high oxidation potentials, was successfully carried out to provide the corresponding acyloxylated products in moderate to excellent yields. Furthermore, it was found that silica gel supported bases are not only chemically stable under acidic conditions but also electrochemically stable and thus reusable for many times.

元の言語English
ページ(範囲)5959-5963
ページ数5
ジャーナルElectrochimica Acta
54
発行部数24
DOI
出版物ステータスPublished - 2009 10 1

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Electrochemistry

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