Anodic acyloxylation based on the acid-base reactions between acetic acid or trifluoroacetic acid and solid-supported bases

Toshiki Tajima, Yuichiro Kishi, Atsushi Nakajima

研究成果: Article査読

18 被引用数 (Scopus)

抄録

We have developed a novel electrolytic system for anodic acyloxylation based on the acid-base reactions between acetic acid or trifluoroacetic acid and solid-supported bases. On the basis of the electrolytic system, anodic acyloxylation of organic compounds, which even have considerably high oxidation potentials, was successfully carried out to provide the corresponding acyloxylated products in moderate to excellent yields. Furthermore, it was found that silica gel supported bases are not only chemically stable under acidic conditions but also electrochemically stable and thus reusable for many times.

本文言語English
ページ(範囲)5959-5963
ページ数5
ジャーナルElectrochimica Acta
54
24
DOI
出版ステータスPublished - 2009 10月 1
外部発表はい

ASJC Scopus subject areas

  • 化学工学(全般)
  • 電気化学

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