Anodic acyloxylation based on the acid-base reactions between acetic acid or trifluoroacetic acid and solid-supported bases

Toshiki Tajima, Yuichiro Kishi, Atsushi Nakajima

研究成果: Article

12 引用 (Scopus)

抄録

We have developed a novel electrolytic system for anodic acyloxylation based on the acid-base reactions between acetic acid or trifluoroacetic acid and solid-supported bases. On the basis of the electrolytic system, anodic acyloxylation of organic compounds, which even have considerably high oxidation potentials, was successfully carried out to provide the corresponding acyloxylated products in moderate to excellent yields. Furthermore, it was found that silica gel supported bases are not only chemically stable under acidic conditions but also electrochemically stable and thus reusable for many times.

元の言語English
ページ(範囲)5959-5963
ページ数5
ジャーナルElectrochimica Acta
54
発行部数24
DOI
出版物ステータスPublished - 2009 10 1
外部発表Yes

Fingerprint

Trifluoroacetic acid
Trifluoroacetic Acid
Silica Gel
Silica gel
Organic compounds
Acetic acid
Acetic Acid
Oxidation
Acids

ASJC Scopus subject areas

  • Electrochemistry
  • Chemical Engineering(all)

これを引用

Anodic acyloxylation based on the acid-base reactions between acetic acid or trifluoroacetic acid and solid-supported bases. / Tajima, Toshiki; Kishi, Yuichiro; Nakajima, Atsushi.

:: Electrochimica Acta, 巻 54, 番号 24, 01.10.2009, p. 5959-5963.

研究成果: Article

@article{57ed7b6ceb3a46ddab397a790c969aa2,
title = "Anodic acyloxylation based on the acid-base reactions between acetic acid or trifluoroacetic acid and solid-supported bases",
abstract = "We have developed a novel electrolytic system for anodic acyloxylation based on the acid-base reactions between acetic acid or trifluoroacetic acid and solid-supported bases. On the basis of the electrolytic system, anodic acyloxylation of organic compounds, which even have considerably high oxidation potentials, was successfully carried out to provide the corresponding acyloxylated products in moderate to excellent yields. Furthermore, it was found that silica gel supported bases are not only chemically stable under acidic conditions but also electrochemically stable and thus reusable for many times.",
keywords = "Acid-base reaction, Anodic acetoxylation, Anodic trifluoroacetoxylation, Solid-supported base, Supporting electrolyte",
author = "Toshiki Tajima and Yuichiro Kishi and Atsushi Nakajima",
year = "2009",
month = "10",
day = "1",
doi = "10.1016/j.electacta.2009.05.067",
language = "English",
volume = "54",
pages = "5959--5963",
journal = "Electrochimica Acta",
issn = "0013-4686",
publisher = "Elsevier Limited",
number = "24",

}

TY - JOUR

T1 - Anodic acyloxylation based on the acid-base reactions between acetic acid or trifluoroacetic acid and solid-supported bases

AU - Tajima, Toshiki

AU - Kishi, Yuichiro

AU - Nakajima, Atsushi

PY - 2009/10/1

Y1 - 2009/10/1

N2 - We have developed a novel electrolytic system for anodic acyloxylation based on the acid-base reactions between acetic acid or trifluoroacetic acid and solid-supported bases. On the basis of the electrolytic system, anodic acyloxylation of organic compounds, which even have considerably high oxidation potentials, was successfully carried out to provide the corresponding acyloxylated products in moderate to excellent yields. Furthermore, it was found that silica gel supported bases are not only chemically stable under acidic conditions but also electrochemically stable and thus reusable for many times.

AB - We have developed a novel electrolytic system for anodic acyloxylation based on the acid-base reactions between acetic acid or trifluoroacetic acid and solid-supported bases. On the basis of the electrolytic system, anodic acyloxylation of organic compounds, which even have considerably high oxidation potentials, was successfully carried out to provide the corresponding acyloxylated products in moderate to excellent yields. Furthermore, it was found that silica gel supported bases are not only chemically stable under acidic conditions but also electrochemically stable and thus reusable for many times.

KW - Acid-base reaction

KW - Anodic acetoxylation

KW - Anodic trifluoroacetoxylation

KW - Solid-supported base

KW - Supporting electrolyte

UR - http://www.scopus.com/inward/record.url?scp=67649195909&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=67649195909&partnerID=8YFLogxK

U2 - 10.1016/j.electacta.2009.05.067

DO - 10.1016/j.electacta.2009.05.067

M3 - Article

AN - SCOPUS:67649195909

VL - 54

SP - 5959

EP - 5963

JO - Electrochimica Acta

JF - Electrochimica Acta

SN - 0013-4686

IS - 24

ER -