Anodic alkoxylation of lactams followed by reactions with carbon nucleophiles in a one-pot manner using HFIP as a solvent

Toshiki Tajima, Hitoshi Kurihara, Shoichi Shimizu, Hiroyuki Tateno

研究成果: Article査読

6 被引用数 (Scopus)

抄録

We have demonstrated anodic alkoxylation of lactams followed by reactions with carbon nucleophiles in a one-pot manner using 1,1,1,3,3,3- hexafluoroisopropanol (HFIP) as a solvent. In the two-step transformation, HFIP acted as a nucleophile in the presence of solid-supported bases, while it acted as an inert solvent in the absence of solidsupported bases. This enabled us to conduct anodic alkoxylation of lactams and subsequent C-C bond forming reactions without replacing the solvent.

本文言語English
ページ(範囲)353-355
ページ数3
ジャーナルElectrochemistry
81
5
DOI
出版ステータスPublished - 2013 5

ASJC Scopus subject areas

  • 電気化学

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