Catalytic asymmetric iodocarbocyclization reaction

Tadashi Inoue, Osamu Kitagawa, Orie Ochiai, Motoo Shiro, Takeo Taguchi

研究成果: Article

42 引用 (Scopus)

抄録

The iodocarbocyclization reactions of 4-pentenylmalonate derivatives using 20 mol% of the chiral titanium complex in the presence of 12 end 2,6-dimethoxypyridine proceeded with high enantioselectivity to give good yields of cyclopentane derivatives. The origin of enantioselectivity in the present reaction is discussed on the basis of X-ray crystal structural data of the chiral titanium complex from acetylacetone, chiral dial and Ti(IV).

元の言語English
ページ（範囲）9333-9336
ページ数4
ジャーナルTetrahedron Letters
巻36
発行部数51
DOI
出版物ステータスPublished - 1995 12 18
外部発表Yes

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Enantioselectivity
Titanium
Derivatives
Cyclopentanes
X rays
Crystals
acetylacetone

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

これを引用

Catalytic asymmetric iodocarbocyclization reaction. / Inoue, Tadashi; Kitagawa, Osamu; Ochiai, Orie; Shiro, Motoo; Taguchi, Takeo.

：: Tetrahedron Letters, 巻 36, 番号 51, 18.12.1995, p. 9333-9336.

研究成果: Article

Inoue, T, Kitagawa, O, Ochiai, O, Shiro, M & Taguchi, T 1995, 'Catalytic asymmetric iodocarbocyclization reaction', Tetrahedron Letters, 巻. 36, 番号 51, pp. 9333-9336. https://doi.org/10.1016/0040-4039(95)02021-G
Inoue T, Kitagawa O, Ochiai O, Shiro M, Taguchi T. Catalytic asymmetric iodocarbocyclization reaction. Tetrahedron Letters. 1995 12 18;36(51):9333-9336. https://doi.org/10.1016/0040-4039(95)02021-G
Inoue, Tadashi ; Kitagawa, Osamu ; Ochiai, Orie ; Shiro, Motoo ; Taguchi, Takeo. / Catalytic asymmetric iodocarbocyclization reaction. ：: Tetrahedron Letters. 1995 ; 巻 36, 番号 51. pp. 9333-9336.
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AU - Taguchi, Takeo

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