Catalytic asymmetric iodocarbocyclization reaction

Tadashi Inoue, Osamu Kitagawa, Orie Ochiai, Motoo Shiro, Takeo Taguchi

研究成果: Article

42 引用 (Scopus)

抜粋

The iodocarbocyclization reactions of 4-pentenylmalonate derivatives using 20 mol% of the chiral titanium complex in the presence of 12 end 2,6-dimethoxypyridine proceeded with high enantioselectivity to give good yields of cyclopentane derivatives. The origin of enantioselectivity in the present reaction is discussed on the basis of X-ray crystal structural data of the chiral titanium complex from acetylacetone, chiral dial and Ti(IV).

元の言語English
ページ(範囲)9333-9336
ページ数4
ジャーナルTetrahedron Letters
36
発行部数51
DOI
出版物ステータスPublished - 1995 12 18
外部発表Yes

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ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

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