Catalytic asymmetric synthesis of optically active atropisomeric anilides through enantioselective N-allylation with chiral Pd-tol-BINAP catalyst

Osamu Kitagawa; Mitsuteru Kohriyama; Takeo Taguchi

doi:10.1021/jo0264271

Catalytic asymmetric synthesis of optically active atropisomeric anilides through enantioselective N-allylation with chiral Pd-tol-BINAP catalyst

Osamu Kitagawa, Mitsuteru Kohriyama, Takeo Taguchi

研究成果: Article › 査読

78 被引用数 (Scopus)

抄録

Catalytic asymmetric N-allylation reaction of ortho-tert-butylanilide derivatives with diallyl carbonate proceeds in the presence of tol-BINAP-Pd catalyst to give chiral N-allyl ortho-tert-butylanilides of 32-44%ee in excellent chemical yields (≥ 90%).

本文言語	English
ページ（範囲）	8682-8684
ページ数	3
ジャーナル	Journal of Organic Chemistry
巻	67
号	24
DOI	https://doi.org/10.1021/jo0264271
出版ステータス	Published - 2002 11月 29
外部発表	はい

ASJC Scopus subject areas

有機化学

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10.1021/jo0264271

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引用スタイル

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abstract = "Catalytic asymmetric N-allylation reaction of ortho-tert-butylanilide derivatives with diallyl carbonate proceeds in the presence of tol-BINAP-Pd catalyst to give chiral N-allyl ortho-tert-butylanilides of 32-44%ee in excellent chemical yields (≥ 90%).",

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