Catalytic asymmetric synthesis of optically active atropisomeric anilides through enantioselective N-allylation with chiral Pd-tol-BINAP catalyst

Osamu Kitagawa, Mitsuteru Kohriyama, Takeo Taguchi

研究成果: Article

57 引用 (Scopus)

抄録

Catalytic asymmetric N-allylation reaction of ortho-tert-butylanilide derivatives with diallyl carbonate proceeds in the presence of tol-BINAP-Pd catalyst to give chiral N-allyl ortho-tert-butylanilides of 32-44%ee in excellent chemical yields (≥ 90%).

元の言語English
ページ(範囲)8682-8684
ページ数3
ジャーナルJournal of Organic Chemistry
67
発行部数24
DOI
出版物ステータスPublished - 2002 11 29
外部発表Yes

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Anilides
Allylation
Carbonates
Derivatives
Catalysts
2-naphthol BINAP

ASJC Scopus subject areas

  • Organic Chemistry

これを引用

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abstract = "Catalytic asymmetric N-allylation reaction of ortho-tert-butylanilide derivatives with diallyl carbonate proceeds in the presence of tol-BINAP-Pd catalyst to give chiral N-allyl ortho-tert-butylanilides of 32-44{\%}ee in excellent chemical yields (≥ 90{\%}).",
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