Catalytic asymmetric synthesis of optically active atropisomeric anilides through enantioselective N-allylation with chiral Pd-tol-BINAP catalyst

Osamu Kitagawa, Mitsuteru Kohriyama, Takeo Taguchi

研究成果: Article

57 引用 (Scopus)

抄録

Catalytic asymmetric N-allylation reaction of ortho-tert-butylanilide derivatives with diallyl carbonate proceeds in the presence of tol-BINAP-Pd catalyst to give chiral N-allyl ortho-tert-butylanilides of 32-44%ee in excellent chemical yields (≥ 90%).

元の言語English
ページ（範囲）8682-8684
ページ数3
ジャーナルJournal of Organic Chemistry
巻67
発行部数24
DOI
出版物ステータスPublished - 2002 11 29
外部発表Yes

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Anilides
Allylation
Carbonates
Derivatives
Catalysts
2-naphthol BINAP

ASJC Scopus subject areas

  • Organic Chemistry

これを引用

Catalytic asymmetric synthesis of optically active atropisomeric anilides through enantioselective N-allylation with chiral Pd-tol-BINAP catalyst. / Kitagawa, Osamu; Kohriyama, Mitsuteru; Taguchi, Takeo.

：: Journal of Organic Chemistry, 巻 67, 番号 24, 29.11.2002, p. 8682-8684.

研究成果: Article

Kitagawa, O, Kohriyama, M & Taguchi, T 2002, 'Catalytic asymmetric synthesis of optically active atropisomeric anilides through enantioselective N-allylation with chiral Pd-tol-BINAP catalyst', Journal of Organic Chemistry, 巻. 67, 番号 24, pp. 8682-8684. https://doi.org/10.1021/jo0264271
Kitagawa O, Kohriyama M, Taguchi T. Catalytic asymmetric synthesis of optically active atropisomeric anilides through enantioselective N-allylation with chiral Pd-tol-BINAP catalyst. Journal of Organic Chemistry. 2002 11 29;67(24):8682-8684. https://doi.org/10.1021/jo0264271
Kitagawa, Osamu ; Kohriyama, Mitsuteru ; Taguchi, Takeo. / Catalytic asymmetric synthesis of optically active atropisomeric anilides through enantioselective N-allylation with chiral Pd-tol-BINAP catalyst. ：: Journal of Organic Chemistry. 2002 ; 巻 67, 番号 24. pp. 8682-8684.
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