Chirality induction through the reversible catenation of coordination rings

Akiko Hori; Akihiko Akasaka; Kumar Biradha; Shigeru Sakamoto; Kentaro Yamaguchi; Makoto Fujita

doi:10.1002/1521-3773(20020902)41:17<3269::AID-ANIE3269>3.0.CO;2-9

Chirality induction through the reversible catenation of coordination rings

Akiko Hori, Akihiko Akasaka, Kumar Biradha, Shigeru Sakamoto, Kentaro Yamaguchi, Makoto Fujita

研究成果: Article › 査読

62 被引用数 (Scopus)

抄録

Switching on chirality: Reversible catenation allows switching between achiral, planar, Pd^II-linked rings containing a pentakis(m-phenylene) unit and a chiral, double-helical conformation of the catenane (see picture). Molecular chirality is induced in the catenane by an ancillary chiral unit on the metal.

本文言語	English
ページ（範囲）	3269-3272
ページ数	4
ジャーナル	Angewandte Chemie - International Edition
巻	41
号	17
DOI	https://doi.org/10.1002/1521-3773(20020902)41:17<3269::AID-ANIE3269>3.0.CO;2-9
出版ステータス	Published - 2002 9 2
外部発表	はい

ASJC Scopus subject areas

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化学 (全般)

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10.1002/1521-3773(20020902)41:17<3269::AID-ANIE3269>3.0.CO;2-9

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AU - Akasaka, Akihiko

AU - Biradha, Kumar

AU - Sakamoto, Shigeru

AU - Yamaguchi, Kentaro

AU - Fujita, Makoto

PY - 2002/9/2

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N2 - Switching on chirality: Reversible catenation allows switching between achiral, planar, PdII-linked rings containing a pentakis(m-phenylene) unit and a chiral, double-helical conformation of the catenane (see picture). Molecular chirality is induced in the catenane by an ancillary chiral unit on the metal.

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KW - Catenanes

KW - Chirality

KW - Helical structures

KW - Palladium

KW - Self-assembly

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Chirality induction through the reversible catenation of coordination rings

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