Chlorine adlayer-templated growth of a hybrid inorganic–organic layered structure on Au(111)

Izabela Irena Rzeznicka, H. Horino, K. Yagyu, T. Suzuki, S. Kajimoto, H. Fukumura

研究成果: Article

抄録

Growth of a hybrid inorganic–organic layered structure on the Au(111) surface using a one-step solution growth is reported. The hybrid structure is consist of 4,4′-bipyridine [4,4′-BiPyH2]2 + cations, Cl anions and Au adatoms, provided from substrate by means of the adsorbate-induced surface phase transition of a surface reconstruction. Its surface and bulk structures were characterized by scanning tunneling microscopy (STM), secondary ion mass spectrometry (SIMS), and Raman spectroscopy. STM results reveal growth of the first [4,4′-BiPyH2]2 + layer on top of the [Formula presented] chlorine overlayer formed on the Au(111) surface. These two layers are found to provide a platform for a following three-dimensional growth facilitated by hydrogen bonding, aurophilic and π–π stacking interactions.

元の言語English
ページ(範囲)46-50
ページ数5
ジャーナルSurface Science
652
DOI
出版物ステータスPublished - 2016 10 1
外部発表Yes

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Chlorine
chlorine
Scanning tunneling microscopy
scanning tunneling microscopy
Surface reconstruction
Adatoms
Adsorbates
Secondary ion mass spectrometry
hybrid structures
Anions
Raman spectroscopy
Cations
Hydrogen bonds
Negative ions
Phase transitions
Positive ions
secondary ion mass spectrometry
adatoms
platforms
anions

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films
  • Materials Chemistry

これを引用

Chlorine adlayer-templated growth of a hybrid inorganic–organic layered structure on Au(111). / Rzeznicka, Izabela Irena; Horino, H.; Yagyu, K.; Suzuki, T.; Kajimoto, S.; Fukumura, H.

:: Surface Science, 巻 652, 01.10.2016, p. 46-50.

研究成果: Article

Rzeznicka, Izabela Irena ; Horino, H. ; Yagyu, K. ; Suzuki, T. ; Kajimoto, S. ; Fukumura, H. / Chlorine adlayer-templated growth of a hybrid inorganic–organic layered structure on Au(111). :: Surface Science. 2016 ; 巻 652. pp. 46-50.
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abstract = "Growth of a hybrid inorganic–organic layered structure on the Au(111) surface using a one-step solution growth is reported. The hybrid structure is consist of 4,4′-bipyridine [4,4′-BiPyH2]2 + cations, Cl anions and Au adatoms, provided from substrate by means of the adsorbate-induced surface phase transition of a surface reconstruction. Its surface and bulk structures were characterized by scanning tunneling microscopy (STM), secondary ion mass spectrometry (SIMS), and Raman spectroscopy. STM results reveal growth of the first [4,4′-BiPyH2]2 + layer on top of the [Formula presented] chlorine overlayer formed on the Au(111) surface. These two layers are found to provide a platform for a following three-dimensional growth facilitated by hydrogen bonding, aurophilic and π–π stacking interactions.",
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AU - Rzeznicka, Izabela Irena

AU - Horino, H.

AU - Yagyu, K.

AU - Suzuki, T.

AU - Kajimoto, S.

AU - Fukumura, H.

PY - 2016/10/1

Y1 - 2016/10/1

N2 - Growth of a hybrid inorganic–organic layered structure on the Au(111) surface using a one-step solution growth is reported. The hybrid structure is consist of 4,4′-bipyridine [4,4′-BiPyH2]2 + cations, Cl anions and Au adatoms, provided from substrate by means of the adsorbate-induced surface phase transition of a surface reconstruction. Its surface and bulk structures were characterized by scanning tunneling microscopy (STM), secondary ion mass spectrometry (SIMS), and Raman spectroscopy. STM results reveal growth of the first [4,4′-BiPyH2]2 + layer on top of the [Formula presented] chlorine overlayer formed on the Au(111) surface. These two layers are found to provide a platform for a following three-dimensional growth facilitated by hydrogen bonding, aurophilic and π–π stacking interactions.

AB - Growth of a hybrid inorganic–organic layered structure on the Au(111) surface using a one-step solution growth is reported. The hybrid structure is consist of 4,4′-bipyridine [4,4′-BiPyH2]2 + cations, Cl anions and Au adatoms, provided from substrate by means of the adsorbate-induced surface phase transition of a surface reconstruction. Its surface and bulk structures were characterized by scanning tunneling microscopy (STM), secondary ion mass spectrometry (SIMS), and Raman spectroscopy. STM results reveal growth of the first [4,4′-BiPyH2]2 + layer on top of the [Formula presented] chlorine overlayer formed on the Au(111) surface. These two layers are found to provide a platform for a following three-dimensional growth facilitated by hydrogen bonding, aurophilic and π–π stacking interactions.

KW - Au(111)

KW - Aurophilic interaction

KW - Bipyridine

KW - Chlorine overlayer

KW - Scanning tunneling microscopy

KW - Tip-enhanced Raman spectroscopy

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