Cooperative and competitive adsorption mechanism of NO2, NO, and H2O on H-type mordenite

Z. M. Wang, T. Arai, M. Kumagai

研究成果査読

24 被引用数 (Scopus)

抄録

To elucidate the interaction mechanism of NOx (NO2 and NO) and H2O on the surface of H-type mordenite (HM), the dynamic adsorption properties of NO2 + H2O + O2 and NO + H2O + O2 mixtures were examined and the surface reaction of NOx and H2O was studied by an in-situ FT-IR spectroscopic method. It was found that NO2 can be dissociatively adsorbed on two kinds of adsorption sites on HM to form nitric acid like species by interacting with Brønsted acid sites, whereas NO + O2 + H2O adsorption is a competitive process of NO oxidation and H2O adsorption without leading to formation of nitric acid like species. The difference between NO2 adsorption sites and NO oxidation sites gives rise to the difference in their breakthrough properties. Adsorption/catalytic reaction models are proposed based on column adsorption and FT-IR results.

本文言語English
ページ(範囲)1864-1871
ページ数8
ジャーナルIndustrial and Engineering Chemistry Research
40
8
DOI
出版ステータスPublished - 2001 4 18
外部発表はい

ASJC Scopus subject areas

  • 化学 (全般)
  • 化学工学(全般)
  • 産業および生産工学

フィンガープリント

「Cooperative and competitive adsorption mechanism of NO<sub>2</sub>, NO, and H<sub>2</sub>O on H-type mordenite」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル