Copolymerization of ethylene and 2-vinylnaphtalene with titanium and zirconium catalysts

Naofumi Naga, Akinori Toyota

研究成果: Article

7 引用 (Scopus)

抜粋

Copolymerization of ethylene and 2-vinylnaphtalene (VN) has been investigated with dimethylsilylene(tetramethylcyclopentadienyl)(N-tert-butyl) titanium dichloride (1) and rac-isopropylidenebis(indenyl)zirconium dichloride (2) using methylaluminoxane as a cocatalyst. The copolymerization gave the corresponding copolymer in good yield. The catalyst 1 showed higher incorporation of VN than the catalyst 2. Thermal properties of the resulting copolymers were investigated by DSC in comparison with those of poly(ethylene-co-styrene), and poly(ethylene-co-VN) showed higher Tg than poly(ethylene-co-styrene).

元の言語English
ページ(範囲)7513-7517
ページ数5
ジャーナルPolymer
45
発行部数22
DOI
出版物ステータスPublished - 2004 10 13

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics
  • Materials Chemistry

フィンガープリント Copolymerization of ethylene and 2-vinylnaphtalene with titanium and zirconium catalysts' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

  • これを引用