Crystal structural determination of SrAID5 with corner-sharing AID6 octahedron chains by x-ray and neutron diffraction

Toyoto Sato, Shigeyuki Takagi, Magnus H. Sørby, Stefano Deledda, Bjørn C. Hauback, Shin Ichi Orimo

研究成果: Article査読

3 被引用数 (Scopus)

抄録

Aluminium-based complex hydrides (alanates) composed of metal cation(s) and complex anion(s), [AlH4 ] or [AlH6]3− with covalent Al–H bonds, have attracted tremendous attention as hydrogen storage materials since the discovery of the reversible hydrogen desorption and absorption reactions on Ti-enhanced NaAlH4. In cases wherein alkaline-earth metals (M) are used as a metal cation, MAlH5 with corner-sharing AlH6 octahedron chains are known to form. The crystal structure of SrAlH5 has remained unsolved although two different results have been theoretically and experimentally proposed. Focusing on the corner-sharing AlH6 octahedron chains as a unique feature of the alkaline-earth metal, we here report the crystal structure of SrAlD5 investigated by synchrotron radiation powder X-ray and neutron diffraction. SrAlD5 was elucidated to adopt an orthorhombic unit cell with a = 4.6226(10) Å, b = 12.6213(30) Å and c = 5.0321(10) Å in the space group Pbcm (No. 57) and Z = 4. The Al–D distances (1.77–1.81 Å) in the corner-sharing AlD6 octahedra matched with those in the isolated [AlD6 ]3− although the D–Al–D angles in the penta-alanates are significantly more distorted than the isolated [AlD6]3−.

本文言語English
論文番号89
ジャーナルCrystals
8
2
DOI
出版ステータスPublished - 2018 2 9
外部発表はい

ASJC Scopus subject areas

  • 化学工学(全般)
  • 材料科学(全般)
  • 凝縮系物理学
  • 無機化学

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