Cyclopentene homo- and copolymers made with early and late transition metal catalysts

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Cyclopentene (CPE) is obtained from one of the C5 fractions of cyclopentadiene, which is a subproduct of cracking naphtha. CPE is prepared by partial hydrogenation of cyclopentadiene or reduction of cyclopentadiene by sodium in liquid nitrogen. CPE is a unique olefin that, owing to its diverse insertion modes, can be polymerized with various transition metal catalysts. Figure 15.1 shows the four types of CPE polymerization insertion and enchainment modes: 1,2-cis-enchainment, 1,2-trans-enchainment, 1,3-cis-enchainment, and 1,3-trans-enchainment.

本文言語English
ホスト出版物のタイトルStereoselective Polymerization with Single-Site Catalysts
出版社CRC Press
ページ399-412
ページ数14
ISBN(電子版)9781420017083
ISBN(印刷版)9781574445794
出版ステータスPublished - 2007 1 1

ASJC Scopus subject areas

  • Engineering(all)
  • Materials Science(all)
  • Chemistry(all)
  • Chemical Engineering(all)

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