Detection of deposition rate of plasma-polymerized films with a quartz crystal microbalance

Shigeru Kurosawa, Kazuya Kashima, Tomoya Hirokawa, Hidenobu Aizawa, Dae Sang Han, Björn Atthoff, Yasuo Yoshimi, Minoru Yoshimoto, Toshihiro Hirotsu, Jöns Hilborn

研究成果: Article

4 引用 (Scopus)

抜粋

The deposition rates of plasma-polymerized (pp-) films of vinyl acetate, vinyl trifluoroacetate, vinyl 2-chloroacetate, vinyl butanoate, vinyl pivalate, vinyl 2-butenoate, vinyl hexanoate and styrene are determined by the quartz crystal microbalance. Using the same polymerization conditions (100 W RF and 100 Pa vapor pressure) for the various monomers, the deposition rates were determined to be constant within the interval measured. The deposition rates of pp-vinyl acetate, pp-vinyl trifluoroacetate, pp-vinyl 2-chloroacetate, pp-vinyl butanoate, pp-vinyl pivalate, pp-vinyl 2-butenoate, vinyl hexanoate and pp-styrene were scattered on the different position of measure on the position of the lower electrode in the plasma polymerization equipment. The average deposition rate of pp-vinyl acetate was 0.28 μg/min. The average deposition rate of pp-vinyl trifluoroacetate was higher by 15 times, and that of pp- vinyl 2-chloroacetate was higher by 23 times than that of pp-vinyl acetate. The average deposition rate depended on the chemical structure of the monomer.

元の言語English
ページ(範囲)33-38
ページ数6
ジャーナルJournal of Photopolymer Science and Technology
13
発行部数1
出版物ステータスPublished - 2000 12 1
外部発表Yes

ASJC Scopus subject areas

  • Polymers and Plastics
  • Organic Chemistry
  • Materials Chemistry

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  • これを引用

    Kurosawa, S., Kashima, K., Hirokawa, T., Aizawa, H., Han, D. S., Atthoff, B., Yoshimi, Y., Yoshimoto, M., Hirotsu, T., & Hilborn, J. (2000). Detection of deposition rate of plasma-polymerized films with a quartz crystal microbalance. Journal of Photopolymer Science and Technology, 13(1), 33-38.