Development of an all-ceramic module with silica membrane tubes for high temperature hydrogen separation

Yasushi Yoshino, Takehiro Suzuki, Hisatomi Taguchi, Mikihiro Nomura, Shin Ichi Nakao, Naotsugu Itoh

研究成果: Article

5 引用 (Scopus)

抄録

Heat resistant hydrogen selective membranes are desired for use as membrane reactors in low-temperature hydrogen production via the steam reforming of hydrocarbons, which are usually operated over 1000K. In addition, developing a multi-tubular type of membrane unit that can process more reactants is becoming more and more important in order to realize the practical use of membrane reactors. In this study, an all-ceramic module consisting of 6 silica membrane tubes with a comparatively large membrane area of around 0.04m2 was fabricated by a counter-diffusion chemical vapor deposition technique. As a result, the H2/N2 ideal separation factor and the H2 permeance of the module were 1300 and 1.910-7molm-2s-1Pa-1 at 873K, respectively. In a 1000-hour thermal stability test for the silica membrane module, it was found that the H2 permeance initially decreased by about 30% and then became steady under P=0.95MPa at 773K.

元の言語English
ページ(範囲)3432-3447
ページ数16
ジャーナルSeparation Science and Technology
43
発行部数13
DOI
出版物ステータスPublished - 2008 1

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Silicon Dioxide
Hydrogen
Silica
Membranes
Temperature
Low temperature production
Steam reforming
Hydrogen production
Hydrocarbons
Chemical vapor deposition
Thermodynamic stability

ASJC Scopus subject areas

  • Chemistry(all)
  • Process Chemistry and Technology
  • Chemical Engineering(all)
  • Filtration and Separation

これを引用

Development of an all-ceramic module with silica membrane tubes for high temperature hydrogen separation. / Yoshino, Yasushi; Suzuki, Takehiro; Taguchi, Hisatomi; Nomura, Mikihiro; Nakao, Shin Ichi; Itoh, Naotsugu.

:: Separation Science and Technology, 巻 43, 番号 13, 01.2008, p. 3432-3447.

研究成果: Article

Yoshino, Yasushi ; Suzuki, Takehiro ; Taguchi, Hisatomi ; Nomura, Mikihiro ; Nakao, Shin Ichi ; Itoh, Naotsugu. / Development of an all-ceramic module with silica membrane tubes for high temperature hydrogen separation. :: Separation Science and Technology. 2008 ; 巻 43, 番号 13. pp. 3432-3447.
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AU - Suzuki, Takehiro

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AU - Nakao, Shin Ichi

AU - Itoh, Naotsugu

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AB - Heat resistant hydrogen selective membranes are desired for use as membrane reactors in low-temperature hydrogen production via the steam reforming of hydrocarbons, which are usually operated over 1000K. In addition, developing a multi-tubular type of membrane unit that can process more reactants is becoming more and more important in order to realize the practical use of membrane reactors. In this study, an all-ceramic module consisting of 6 silica membrane tubes with a comparatively large membrane area of around 0.04m2 was fabricated by a counter-diffusion chemical vapor deposition technique. As a result, the H2/N2 ideal separation factor and the H2 permeance of the module were 1300 and 1.910-7molm-2s-1Pa-1 at 873K, respectively. In a 1000-hour thermal stability test for the silica membrane module, it was found that the H2 permeance initially decreased by about 30% and then became steady under P=0.95MPa at 773K.

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