Development of an electrolytic system for non-kolbe electrolysis based on the acid-base reaction between carboxylic acids as a substrate and solid-supported bases

Toshiki Tajima, Hitoshi Kurihara, Toshio Fuchigami

研究成果: Article査読

58 被引用数 (Scopus)

抄録

We have successfully developed a novel electrolytic system for non-Kolbe electrolysis based on the acid-base reaction between carboxylic acids as a substrate and solid-supported bases. It was found that the acid-base reaction between carboxylic acids and solid-supported basespreferentially takes place to reduce the cell voltage in MeOH. On the basis of the electrolytic system, non-Kolbe electrolysis of various carboxylic acids was carried out to provide the corresponding methoxylated products in excellent yields.

本文言語English
ページ(範囲)6680-6681
ページ数2
ジャーナルJournal of the American Chemical Society
129
21
DOI
出版ステータスPublished - 2007 5月 30
外部発表はい

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)
  • 生化学
  • コロイド化学および表面化学

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