Development of an electrolytic system using solid-supported bases for in situ generation of a supporting electrolyte from methanol as a solvent

Toshiki Tajima, Toshio Fuchigami

研究成果: Article査読

53 被引用数 (Scopus)

抄録

We have successfully developed a novel electrolytic system using solid-supported bases for in situ generation of a supporting electrolyte from methanol as a solvent. Anodic methoxylation of phenyl 2,2,2-trifluoroethyl sulfide using solid-supported bases was carried out to provide the α-methoxylated product in good to excellent yields. The α-methoxylated product and solid-supported bases were easily separated by only filtration, and the separated solid-supported bases were recyclable. Anodic methoxylation of phenyl 2,2,2-trifluoroethyl sulfide was successfully carried out 10 times by the recycling of silica gel-supported piperidine in good yields.

本文言語English
ページ(範囲)2848-2849
ページ数2
ジャーナルJournal of the American Chemical Society
127
9
DOI
出版ステータスPublished - 2005 3 9
外部発表はい

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)
  • 生化学
  • コロイド化学および表面化学

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