抄録
We have successfully developed a novel electrolytic system using solid-supported bases for in situ generation of a supporting electrolyte from methanol as a solvent. Anodic methoxylation of phenyl 2,2,2-trifluoroethyl sulfide using solid-supported bases was carried out to provide the α-methoxylated product in good to excellent yields. The α-methoxylated product and solid-supported bases were easily separated by only filtration, and the separated solid-supported bases were recyclable. Anodic methoxylation of phenyl 2,2,2-trifluoroethyl sulfide was successfully carried out 10 times by the recycling of silica gel-supported piperidine in good yields.
本文言語 | English |
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ページ(範囲) | 2848-2849 |
ページ数 | 2 |
ジャーナル | Journal of the American Chemical Society |
巻 | 127 |
号 | 9 |
DOI | |
出版ステータス | Published - 2005 3月 9 |
外部発表 | はい |
ASJC Scopus subject areas
- 触媒
- 化学 (全般)
- 生化学
- コロイド化学および表面化学